Digermane, 1-methoxy-1,1,2,2-tetrakis(2,4,6-trimethylphenyl)-

Base Information

• Chemical Name: Digermane, 1-methoxy-1,1,2,2-tetrakis(2,4,6-trimethylphenyl)-
• CAS No.: 136131-70-9
• Molecular Formula: C₃₇H₄₈Ge₂O
• Molecular Weight: 653.968
• Mol file: 136131-70-9.mol

Synonyms:

Chemical Property of Digermane, 1-methoxy-1,1,2,2-tetrakis(2,4,6-trimethylphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Digermane, 1-methoxy-1,1,2,2-tetrakis(2,4,6-trimethylphenyl)-

There total 5 articles about Digermane, 1-methoxy-1,1,2,2-tetrakis(2,4,6-trimethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

methanol (67-56-1) + tetrakis(2,4,6-trimethylphenyl)digermene (115385-07-4) → 1,1,2,2-tetramesitylmethoxydigermane (136131-70-9)

Guidance literature:

In tetrahydrofuran; methanol; (N2); addn. of MeOH (excess) to soln. of (mesityl)4Ge2 in THF at room temp.; evapn. of solvent by rotary evapn.;

DOI:10.1021/om7005358

Reference yield: 30.0%

methanol (67-56-1) + hexamesitylcyclotrigermane (107824-84-0) → 1,1,2,2-tetramesitylmethoxydigermane (136131-70-9)

Guidance literature:

In tetrahydrofuran; methanol; Irradiation (UV/VIS); (N2); dissolving of Ge3(mesityl)6 in THF in Schlenk tube; irradn. at -70°C; addn. of MeOH to cooled soln. (dry ice/acetone);

DOI:10.1021/om7005358

Reference yield:

hexamesitylcyclotrigermane (107824-84-0) → 1,1,2,2-tetramesitylmethoxydigermane (136131-70-9)

Guidance literature:

With CH₃OH; In cyclohexane; Irradiation (UV/VIS); (Ar); 4 h at room temp., then addn. of MeOH;

DOI:10.1039/c39920001484

upstream raw materials:

hexamesitylcyclotrigermane

methanol

tetrakis(2,4,6-trimethylphenyl)digermene

3,3,4,4-tetramesityl-3,4-digermadioxetane