Dichloro(norbornadiene)platinum(II)

Base Information

• Chemical Name: Dichloro(norbornadiene)platinum(II)
• CAS No.: 12152-26-0
• Molecular Formula: C7H8 Cl2 Pt
• Molecular Weight: 358.127
• European Community (EC) Number: 235-271-6
• Mol file: 12152-26-0.mol

Synonyms:Dichloro(norbornadiene)platinum(II);12152-26-0;DICHLORO(NORBORNADIENE)PLATINUM (II);Bicyclo[2.2.1]hepta-2,5-diene;dichloroplatinum;platinum(2+);dichloride;SCHEMBL3852395;MFCD00213423;Dichloro(norbornadiene)platinum(II), 97%;F74349

Chemical Property of Dichloro(norbornadiene)platinum(II)

Chemical Property:

• Melting Point: 186-218°C (decomposition)
• Boiling Point: 89.5°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.82980
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 356.965100
• Heavy Atom Count: 10
• Complexity: 106

Purity/Quality:

99% ^*data from raw suppliers

Dichloro(norbornadiene)platinum(II) 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C2C=CC1C=C2.Cl[Pt]Cl

Technology Process of Dichloro(norbornadiene)platinum(II)

There total 6 articles about Dichloro(norbornadiene)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

potassium tetrachloroplatinate(II) (10025-99-7) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → dichloro-(η**(4)-bicyclo[2.2.1]hepta-2,5-diene)platinum(II) (12152-26-0)

Guidance literature:

In water; isopropyl alcohol; at 70 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejic.201402954

Reference yield: 78.0%

dihydrogen hexachloroplatinate + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → dichloro-(η**(4)-bicyclo[2.2.1]hepta-2,5-diene)platinum(II) (12152-26-0)

Guidance literature:

With NaOH; TBACl; N₂H₄*2HCl; In water; 1,2-dichloro-ethane; under N2; to mixt. of aq. H2PtCl6, ClCH2CH2Cl, water, TBACl and diene added soln. of NaOH in portions until basic pH of aq. layer; then N2H4*2HCl in H2O added under stirring at room temp/; refluxed for 6 h; aq. layer discarded; ppt. washed with heptane, dried in vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2010.12.043

Reference yield: 60.0%

dichlorobis(diethyl sulfide)platinum (14873-92-8) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → dichloro(2,3,5,6-η4-bicyclo{2.2.1}hepta-2,5-dien)platinum(II) (12152-26-0)

Guidance literature:

In neat (no solvent); refluxing in excess of NBD for 4 h (crystn.); collection (filtration), washing (hexane), drying (vac.); elem. anal.;

DOI:10.1039/DT9760000289

upstream raw materials:

dichlorobis(diethyl sulfide)platinum

bicyclo[2.2.1]hepta-2,5-diene

potassium tetrachloroplatinate(II)

cis-dicarbonyldichloroplatinum(II)

Downstream raw materials:

trimethyltin(IV)chloride

cis-dimethylbis[(sulfinyl-κS)bis[methane]]platinum(II)