CID 11045490

Base Information

• Chemical Name: CID 11045490
• CAS No.: 25478-60-8
• Molecular Formula: C₂Cl₂O₂Pt
• Molecular Weight: 322.007
• Mol file: 25478-60-8.mol

Synonyms:

Chemical Property of CID 11045490

Chemical Property:

• PSA: 0.00000
• LogP: 0.00000
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 320.892329
• Heavy Atom Count: 7
• Complexity: 12.8

Purity/Quality:

99% ^*data from raw suppliers

cis-Dichlorodicarbonylplatinum(II), (99.9%-Pt) (99.9%-Pt) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].Cl[Pt]Cl

Technology Process of CID 11045490

There total 36 articles about CID 11045490 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

tetrabutylammonium tetrachloroplatinate + carbon monoxide (201230-82-2) → cis-dicarbonyldichloroplatinum(II) (25478-60-8,15020-32-3,62841-60-5)

Guidance literature:

With AlCl₃; In dichloromethane; stirring (1 atm CO, room temp., 12 h); addn. of heptane, cooling to -30°C, filtration;

Reference yield: 92.0%

sulfuryl dichloride (7791-25-5) + carbon monoxide (201230-82-2) + platinum (7440-06-4) → cis-dicarbonyldichloroplatinum(II) (25478-60-8,15020-32-3,62841-60-5)

Guidance literature:

In thionyl chloride; addn. of platinum black to soln. of SO2Cl2 in SOCl2 under CO; after 150h soln. evapd. and residue dissolved in toluene; detn. by IR;

DOI:10.1016/S0022-328X(99)00581-1

Reference yield: 90.0%

sulfuryl dichloride (7791-25-5) + [PtI2(CO)2] (106863-38-1,77828-68-3,106863-42-7) + tetraiodo-dicarbonyl-diplatinum(II) + carbon monoxide (201230-82-2) → cis-dicarbonyldichloroplatinum(II) (25478-60-8,15020-32-3,62841-60-5)

Guidance literature:

In toluene; work-up with toluene and heptane;

upstream raw materials:

[PtI₂(CO)2]

sulfuryl dichloride

carbon monoxide

cis-dichlorobis(propiononitrile)platinum(II)

Downstream raw materials:

dichloro( 1,5-cyclooctadiene)platinum(ll)

hydrogenchloride

carbon dioxide

cis-dichlorobis(triethylphosphine)platinum(II)