8-Fluoro-1,4-dioxaspiro[4.5]dec-7-ene

Base Information

Chemical Name:8-Fluoro-1,4-dioxaspiro[4.5]dec-7-ene
CAS No.:142273-44-7
Molecular Formula:C8H11FO2
Molecular Weight:
Hs Code.:
DSSTox Substance ID:DTXSID90576562
Nikkaji Number:J455.564C
Wikidata:Q82466331

Synonyms:8-Fluoro-1,4-dioxaspiro[4.5]dec-7-ene;142273-44-7;8-fluoro-1,4-dioxa-spiro[4.5]dec-7-ene;SCHEMBL5491921;DTXSID90576562;PUFPTTSOKWIOJA-UHFFFAOYSA-N;CS-0120529

Suppliers and Price of 8-Fluoro-1,4-dioxaspiro[4.5]dec-7-ene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 8-Fluoro-1,4-dioxaspiro[4.5]dec-7-ene

Chemical Property:

XLogP3:1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:158.07430775
Heavy Atom Count:11
Complexity:183

Purity/Quality:: NLT 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2(CC=C1F)OCCO2

Technology Process of 8-Fluoro-1,4-dioxaspiro[4.5]dec-7-ene

There total 3 articles about 8-Fluoro-1,4-dioxaspiro[4.5]dec-7-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 4746-97-8
cyclohexanedione monoethylene ketal

: 142273-44-7
8-fluoro-1,4-dioxaspiro[4.5]dec-7-ene

Guidance literature:: With diethylamino-sulfur trifluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 10 - 25 ℃; for 12h; Reagent/catalyst; Solvent;

Reference yield: 60.0%

: 4746-97-8
cyclohexanedione monoethylene ketal

: 176251-49-3
8,8-difluoro-1,4-dioxaspiro[4,5]decane

: 142273-44-7
8-fluoro-1,4-dioxaspiro[4.5]dec-7-ene

Guidance literature:: With pyrrolidinodifluorosulfiniumtetrafluoroborate; triethylamine tris(hydrogen fluoride); In dichloromethane; at 20 ℃; for 3h; Reagent/catalyst; Inert atmosphere;
DOI:10.1016/j.jfluchem.2013.05.019

Reference yield: 35.0%

: 142273-39-0
8-trimethylstannyl-1,4-dioxaspiro[4.5]dec-7-ene

: 142273-44-7
8-fluoro-1,4-dioxaspiro[4.5]dec-7-ene

Guidance literature:: With xenon difluoride; silver(I) hexafluorophosphate; In dichloromethane; at 25 ℃; for 6h;
DOI:10.1080/00397919208021614