Methyl-4-oxo-4-phenyl-2-butenoate

Base Information

Chemical Name:Methyl-4-oxo-4-phenyl-2-butenoate
CAS No.:14274-07-8
Molecular Formula:C11H10 O3
Molecular Weight:190.199
Hs Code.:2918300090
NSC Number:49218
Nikkaji Number:J1.689.957G,J488.582A
ChEMBL ID:CHEMBL296423
Mol file:14274-07-8.mol

Synonyms:Methyl-4-oxo-4-phenyl-2-butenoate;14274-07-8;methyl 4-oxo-4-phenylbut-2-enoate;methyl (E)-4-oxo-4-phenylbut-2-enoate;methyl 3-benzoylacrylate;19522-25-9;methyl (2E)-4-oxo-4-phenylbut-2-enoate;NSC49218;CHEMBL296423;SCHEMBL3031262;methyl trans-beta-benzoylacrylate;methyl4-oxo-4-phenylbut-2-enoate;NSC-49218;AKOS005100231;(E)-3-Benzoylacrylic acid methyl ester;Methyl(E)-4-oxo-4-phenyl-2-butenoate;(E)-methyl 4-oxo-4-phenylbut-2-enoate;methyl (E)-4-oxo-4-phenyl-but-2-enoate;BB 0218787;CS-0347187;4-Oxo-4-phenyl-2-butenoic acid methyl ester;EN300-37144;7N-715;A807960;(E)-4-Oxo-4-phenyl-but-2-enoic acid methyl ester;Z381040998

Suppliers and Price of Methyl-4-oxo-4-phenyl-2-butenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
METHYL (2E)-4-OXO-4-PHENYLBUT-2-ENOATE 95.00%
5G
$ 1421.65

American Custom Chemicals Corporation
METHYL (2E)-4-OXO-4-PHENYLBUT-2-ENOATE 95.00%
2.5G
$ 1147.43

American Custom Chemicals Corporation
METHYL (2E)-4-OXO-4-PHENYLBUT-2-ENOATE 95.00%
1G
$ 808.89

Total 8 raw suppliers

Chemical Property of Methyl-4-oxo-4-phenyl-2-butenoate

Chemical Property:

Vapor Pressure:0.0022mmHg at 25°C
Boiling Point:289.5°Cat760mmHg
Flash Point:125.1°C
PSA：43.37000
Density:1.134g/cm³
LogP:1.59850
XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:190.062994177
Heavy Atom Count:14
Complexity:237

Purity/Quality:

97% ^*data from raw suppliers

METHYL (2E)-4-OXO-4-PHENYLBUT-2-ENOATE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C=CC(=O)C1=CC=CC=C1
Isomeric SMILES:COC(=O)/C=C/C(=O)C1=CC=CC=C1

Technology Process of Methyl-4-oxo-4-phenyl-2-butenoate

There total 59 articles about Methyl-4-oxo-4-phenyl-2-butenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 27117-69-7,27117-70-0,56742-96-2,56742-97-3
Methyl-erythro-2,3-dibrom-4-oxo-4-phenylbutanoat

: 14274-07-8
methyl trans-β-benzoylacrylate

Guidance literature:: With indium; iron(III) chloride hexahydrate; In methanol; at 20 ℃; for 2h; chemoselective reaction;
DOI:10.1080/00397910802531989

Reference yield: 90.0%

: 27117-69-7,27117-70-0,56742-96-2,56742-97-3
(+/-)-erythro-2.3-dibromo-4-oxo-4-phenyl-butyric acid methyl ester

: 14274-07-8
methyl trans-β-benzoylacrylate

Guidance literature:: With indium; In methanol; at 30 ℃; for 12h;
DOI:10.1039/a806530f

Reference yield: 90.0%

: 201230-82-2
carbon monoxide

: 17763-67-6
Phenyl triflate

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 14274-07-8,19522-25-9,19522-28-2
methyl 3-benzoylacrylate

Guidance literature:: With palladium diacetate; caesium carbonate; In water; at 35 - 95 ℃; under 3750.38 Torr; Schlenk technique; Inert atmosphere;
DOI:10.1039/c8cc00324f