10-Undecenoic acid, 4-nitrophenyl ester

Base Information

• Chemical Name: 10-Undecenoic acid, 4-nitrophenyl ester
• CAS No.: 151309-96-5
• Molecular Formula: C17H23NO4
• Molecular Weight: 305.374
• Mol file: 151309-96-5.mol

Synonyms:

Chemical Property of 10-Undecenoic acid, 4-nitrophenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10-Undecenoic acid, 4-nitrophenyl ester

There total 3 articles about 10-Undecenoic acid, 4-nitrophenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + undec-10-enoyl chloride (38460-95-6) → 4-nitrophenyl ω-undecenoate (151309-96-5)

Guidance literature:

With pyridine; In diethyl ether; for 2h; Reflux;

Reference yield: 98.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + 10-undecenoic acid (112-38-9) → 4-nitrophenyl ω-undecenoate (151309-96-5)

Guidance literature:

With dicyclohexyl-carbodiimide; In acetonitrile; at 25 ℃; for 1h;

DOI:10.1039/b312559a

Reference yield: 78.0%

10-undecenoic acid (112-38-9) + 4-Nitrophenyl chloroformate (7693-46-1) → 4-nitrophenyl ω-undecenoate (151309-96-5)

Guidance literature:

10-undecenoic acid; With triethylamine; In dichloromethane; for 0.166667h; Inert atmosphere;

4-Nitrophenyl chloroformate; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1039/c4cc09003a

upstream raw materials:

4-nitro-phenol

10-undecenoic acid

undec-10-enoyl chloride

4-Nitrophenyl chloroformate

Downstream raw materials:

1,10-decadiene

trans,trans-2,8-decadiene

dipropyl-1,3-butadiene

C₃₁H₅₁NO₅

Refernces

• 1、 Nielsen, Anne L.,Steffensen, Kim,Wimmer, Reinhard,Worm-Leonhard, Martin,Larsen, Kim L.. "Syntheses and characterisation of novel cyclodextrin vinyl derivatives from cyclodextrin-nitrophenol-derivatives". . p. 303 - 315. Retrieved 2010.
• 2、 John, Alex,Dereli, Büsra,Ortunìo, Manuel A.,Johnson, Hillis E.,Hillmyer, Marc A.,Cramer, Christopher J.,Tolman, William B.. "Selective Decarbonylation of Fatty Acid Esters to Linear α-Olefins". . p. 2956 - 2964. Retrieved 2017/08/21.