4-tert-butylphenyl benzoate

Base Information

• Chemical Name: 4-tert-butylphenyl benzoate
• CAS No.: 14041-81-7
• Molecular Formula: C17H18O2
• Molecular Weight: 254.329
• Mol file: 14041-81-7.mol

Synonyms:

Chemical Property of 4-tert-butylphenyl benzoate

Chemical Property:

• Vapor Pressure: 2.73E-05mmHg at 25°C
• Boiling Point: 357.4°Cat760mmHg
• Flash Point: 149.2°C
• Density: 1.061g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-tert-butylphenyl benzoate

There total 16 articles about 4-tert-butylphenyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

iodobenzene (591-50-4) + para-tert-butylphenol (98-54-4) + carbon monoxide (201230-82-2) → 4-tert-butylphenyl benzoate (14041-81-7)

Guidance literature:

With N,N-dimethyl acetamide; triethylamine; at 100 ℃; for 4h; under 15001.5 Torr; Autoclave;

DOI:10.1007/s11243-014-9818-9

Reference yield: 96.0%

para-tert-butylphenol (98-54-4) + benzoyl chloride (98-88-4) → 4-tert-butylphenyl benzoate (14041-81-7)

Guidance literature:

In pyridine; for 1.16667h; Cooling with ice;

DOI:10.1021/acs.joc.9b00334

Reference yield: 94.0%

para-tert-butylphenol (98-54-4) + benzaldehyde (100-52-7) → 4-tert-butylphenyl benzoate (14041-81-7)

Guidance literature:

With Phenazin; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dimethyl sulfoxide; at 40 ℃; for 18h; Schlenk technique; Sealed tube; Inert atmosphere;

DOI:10.1021/acs.orglett.7b01617

upstream raw materials:

sodium benzoate

tri-p-tert-butylphenol phosphate ester

para-tert-butylphenol

benzoyl chloride

Downstream raw materials:

tin

(Benzoyloxy)tributylstannan

(C₄H₉)3SnOC₆H₄(C₄H₉)

para-tert-butylphenol

Refernces

• 1、 Zheng, Lei,Sun, Chen,Xu, Wenhao,Dushkin, Alexandr V.,Polyakov, Nikolay,Su, Weike,Yu, Jingbo. "Mechanically induced solvent-free esterification method at room temperature". . p. 5080 - 5085. Retrieved 2021/02/05.
• 2、 Ishida, Naoki,Kawasaki, Tairin,Murakami, Masahiro,Tosaki, Tomohiro. "Visible-Light-Driven Dehydrogenative Coupling of Primary Alcohols with Phenols Forming Aryl Carboxylates". supporting information. p. 7683 - 7687. Retrieved 2021/10/12.