1,4-Bis(prop-2-en-1-yloxy)benzene

Base Information

• Chemical Name: 1,4-Bis(prop-2-en-1-yloxy)benzene
• CAS No.: 37592-20-4
• Molecular Formula: C12H14 O2
• Molecular Weight: 190.242
• Hs Code.: 2909309090
• NSC Number: 74761
• DSSTox Substance ID: DTXSID50291305
• Nikkaji Number: J1.067.553G
• Wikidata: Q82029222
• ChEMBL ID: CHEMBL2252608
• Mol file: 37592-20-4.mol

Synonyms:1,4-bis(prop-2-en-1-yloxy)benzene;1,4-Bis(allyloxy)benzene;37592-20-4;Benzene, p-bis(allyloxy)-;Benzene, 1,4-bis(allyloxy)-;NIOSH/CY8312500;CY83125000;1,4-bis(prop-2-enoxy)benzene;NSC74761;1,4-diallyloxy ben-zene;1,4-DIALLYLOXYBENZENE;SCHEMBL302448;CHEMBL2252608;DTXSID50291305;NSC-74761

Chemical Property of 1,4-Bis(prop-2-en-1-yloxy)benzene

Chemical Property:

• Vapor Pressure: 0.00502mmHg at 25°C
• Boiling Point: 284.7°Cat760mmHg
• Flash Point: 109.3°C
• PSA: 18.46000
• Density: 0.982g/cm³
• LogP: 2.81620
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 6
• Exact Mass: 190.099379685
• Heavy Atom Count: 14
• Complexity: 149

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCOC1=CC=C(C=C1)OCC=C

Technology Process of 1,4-Bis(prop-2-en-1-yloxy)benzene

There total 9 articles about 1,4-Bis(prop-2-en-1-yloxy)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

allyl bromide (106-95-6) + hydroquinone (123-31-9,8027-02-9) → 1,4-bis(allyloxy)benzene (37592-20-4)

Guidance literature:

allyl bromide; With sodium hydride; In N,N-dimethyl-formamide; oil; at -10 ℃; for 0.166667h;

hydroquinone; In N,N-dimethyl-formamide; oil; for 0.75h;

DOI:10.1016/j.tet.2010.10.018

Reference yield: 96.0%

allyl methyl carbonate (35466-83-2) + hydroquinone (123-31-9,8027-02-9) → 1,4-bis(allyloxy)benzene (37592-20-4)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In tetrahydrofuran; at 25 ℃; for 24h;

DOI:10.1080/00397910008086955

Reference yield: 81.0%

hydroquinone (123-31-9,8027-02-9) + 3-chloroprop-1-ene (107-05-1) → 1,4-bis(allyloxy)benzene (37592-20-4)

Guidance literature:

With zinc; In N,N-dimethyl-formamide; for 0.141667h; microwave irradiation;

DOI:10.1016/j.tetlet.2004.10.009

upstream raw materials:

allyl bromide

hydroquinone

allyl methyl carbonate

Allyl acetate

Downstream raw materials:

2-((4-(allyloxy)phenoxy)methyl)oxirane

2,5-diallyl-1,4-hydroquinone

2,3-diallyl-1,4-dihydrobenzoquinone

1,4-bis(oxiran-2-ylmethoxy)benzene