Silane, dimethyl(2-methyl-1-oxopropyl)phenyl-

Base Information

Chemical Name:Silane, dimethyl(2-methyl-1-oxopropyl)phenyl-
CAS No.:155397-24-3
Molecular Formula:C12H18OSi
Molecular Weight:206.36
Hs Code.:
DSSTox Substance ID:DTXSID70434510
Nikkaji Number:J1.865.982D
Wikidata:Q82248950
Mol file:155397-24-3.mol

Synonyms:Silane, dimethyl(2-methyl-1-oxopropyl)phenyl-;155397-24-3;DTXSID70434510;Isopropyl(phenyldimethylsilyl) ketone

Suppliers and Price of Silane, dimethyl(2-methyl-1-oxopropyl)phenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Silane, dimethyl(2-methyl-1-oxopropyl)phenyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:206.112691728
Heavy Atom Count:14
Complexity:202

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)C(=O)[Si](C)(C)C1=CC=CC=C1

Technology Process of Silane, dimethyl(2-methyl-1-oxopropyl)phenyl-

There total 8 articles about Silane, dimethyl(2-methyl-1-oxopropyl)phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 75-30-9
2-iodo-propane

: 201230-82-2
carbon monoxide

: 185990-03-8
dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

: 155397-24-3
1-[dimethyl(phenyl)vinyl]-2-methylpropan-1-one

Guidance literature:: With chloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]copper(I); sodium phenoxide; In 1,4-dioxane; at 60 ℃; for 12h; under 4560.31 Torr; Glovebox;
DOI:10.1021/jacs.9b12043

Reference yield: 82.0%

: 155397-18-5
2-methyl-1,1-bispropan-1-ol

: 155397-24-3
1-[dimethyl(phenyl)vinyl]-2-methylpropan-1-one

Guidance literature:: With tetrachloromethane; n-butyllithium; In diethyl ether; hexane; at -40 ℃; for 12h;
DOI:10.1002/1522-2675(200210)85:10<3349::AID-HLCA3349>3.0.CO;2-K

Reference yield:

: 768-33-2
phenyldimethylsilyl chloride

: 155397-24-3
1-[dimethyl(phenyl)vinyl]-2-methylpropan-1-one

Guidance literature:: Multi-step reaction with 2 steps

1.1: Li / tetrahydrofuran / 40 h / 0 °C

2.1: tetrahydrofuran / 1.5 h / -78 °C

2.2: 60 percent / aq. NH₄Cl / tetrahydrofuran / -78 - 20 °C

With lithium; In tetrahydrofuran;
DOI:10.1021/ol0483854