2'-(Diphenylphosphino)-[1,1'-biphenyl]-2-ol

Base Information

• Chemical Name: 2'-(Diphenylphosphino)-[1,1'-biphenyl]-2-ol
• CAS No.: 155566-51-1
• Molecular Formula: C24H19OP
• Molecular Weight: 354.388
• DSSTox Substance ID: DTXSID80371280
• Nikkaji Number: J2.263.265E
• Wikidata: Q82158565
• Mol file: 155566-51-1.mol

Synonyms:155566-51-1;2'-(Diphenylphosphino)-[1,1'-biphenyl]-2-ol;[1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphino)-;2-hydroxy-2'-diphenylphosphino biphenyl;SCHEMBL2322069;DTXSID80371280;RTFMVYDUGUHDJT-UHFFFAOYSA-N;2'-(Diphenylphosphino)biphenyl-2-ol;2'-hydroxy-2-diphenylphosphinobiphenyl;2-diphenylphosphino-2'-hydroxy biphenyl;2'-(Diphenylphosphino)-[1,1'-biphenyl]-2-ol 98%

Chemical Property of 2'-(Diphenylphosphino)-[1,1'-biphenyl]-2-ol

Chemical Property:

• XLogP3: 5.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 354.117352223
• Heavy Atom Count: 26
• Complexity: 394

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3C4=CC=CC=C4O

Technology Process of 2'-(Diphenylphosphino)-[1,1'-biphenyl]-2-ol

There total 6 articles about 2'-(Diphenylphosphino)-[1,1'-biphenyl]-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

p-chlorodibenzo[c.e][1,2]oxaphosphorine (22749-43-5) + phenylmagnesium bromide → 2'-hydroxy-2-diphenylphosphinobiphenyl (155566-51-1)

Guidance literature:

In tetrahydrofuran; at 26 ℃; for 20h;

DOI:10.1016/j.jorganchem.2006.08.080

Reference yield: 70.0%

p-chlorodibenzo[c.e][1,2]oxaphosphorine (22749-43-5) + phenylmagnesium bromide → 2'-hydroxy-2-diphenylphosphinobiphenyl (155566-51-1) + 6-Phenyl-6H-dibenzo[c,e][1,2]oxaphosphorine (139995-03-2)

Guidance literature:

In tetrahydrofuran; diethyl ether; at 26 ℃; for 20h;

DOI:10.1002/hc.20042

Reference yield:

p-chlorodibenzo[c.e][1,2]oxaphosphorine (22749-43-5) + phenylmagnesium bromide (100-58-3) → 2'-hydroxy-2-diphenylphosphinobiphenyl (155566-51-1)

Guidance literature:

In tetrahydrofuran; water; ethyl acetate;

upstream raw materials:

(+/-)-2-(diphenylphosphinyo)-2'-<<(trifluoromethyl)sulfonyl>oxy>biphenyl

dibenzofuran

chloro-diphenylphosphine

p-chlorodibenzo[c.e][1,2]oxaphosphorine

Downstream raw materials:

(2'-diphenylphosphino-biphenyl-2-yl)-oxydibenzo[c.e][5,6]oxaphosphorine

(2'-benzyloxybiphenyl-2-yl)diphenylphosphine

(2'-hydroxy-biphenyl-2-yl)-diphenylphosphane borane

bis((2'-hydroxy-biphenyl-2-yl)-diphenylphosphine)-dichloro-platinum(II)

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 155566-51-1 [1,1'-Biphenyl]-2-ol, 2'-(diphenylphosphino)-

Send

Send

Metric Ton KG G Pound L ML

Send

Send