Rhodium, carbonyltrichlorobis(triphenylphosphine)-

Base Information

Chemical Name:Rhodium, carbonyltrichlorobis(triphenylphosphine)-
CAS No.:16969-79-2
Molecular Formula:C₃₇H₃₀Cl₃OP₂Rh
Molecular Weight:761.857
Hs Code.:
Mol file:16969-79-2.mol

Synonyms:

Suppliers and Price of Rhodium, carbonyltrichlorobis(triphenylphosphine)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Rhodium, carbonyltrichlorobis(triphenylphosphine)-

Chemical Property:

Purity/Quality:: 99.90% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of Rhodium, carbonyltrichlorobis(triphenylphosphine)-

There total 15 articles about Rhodium, carbonyltrichlorobis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 14694-95-2
Wilkinson's catalyst

: 76-03-9
trichloroacetic acid

: 16969-79-2,24322-80-3
Rh(CO)(P(C₆H₅)3)2Cl₃

Guidance literature:: In benzene; Rh-complex was added to a soln. of Cl3CCOOH in benzene (1:3 ratio), mixt. was stirred at ambient temp. for 8 h under N2;

Reference yield: 72.0%

: 17185-29-4
carbonylhydridetris(triphenylphosphine)rhodium(I)

: 76-03-9
trichloroacetic acid

: 16969-79-2,24322-80-3
Rh(CO)(P(C₆H₅)3)2Cl₃

Guidance literature:: In benzene; a mixt. of Rh-complex and Cl3CCOOH was stirred in benzene at ambient temp. for 2 h under N2; evapd. to near dryness, residue was treated with MeOH, washed with MeOHand hexane, dried in vac.;

Reference yield: 71.0%

: 19399-77-0
Na⁽¹⁺⁾*[Rh(CO)2(P(C₆H₅)3)2]^(1-)=Na[Rh(CO)2(P(C₆H₅)3)2]

: 76-02-8
trifluoroacetyl chloride

: 16969-79-2,24322-80-3
Rh(CO)(P(C₆H₅)3)2Cl₃

Guidance literature:: In tetrahydrofuran; byproducts: carbon monoxide; 1:2 stoich. ratio of Rh-complex and trichloroacetyl chloride in THF stirred at room temp. for 1 h under CO; chromd.;
DOI:10.1016/S0022-328X(00)90025-1