Technology Process of Boronic acid, [2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-, dimethyl ester
There total 1 articles about Boronic acid, [2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-, dimethyl ester which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
t-BuLi; NH4Cl;
In
tetrahydrofuran; water; pentane;
Ar-atmosphere; stirring (-78°C, 60 min), B(OMe)3 addn., stirring (to room temp., 10 h), NH4Cl satd. soln. (H2O) addn.; extg. (hexane), drying (MgSO4), evapn. (reduced pressure), chromy. (SiO2, hexane), repptn. (CH2Cl2 / EtOH); elem. anal.;
DOI:10.1021/om970328+
- Guidance literature:
-
With
NH4Cl;
In
tetrahydrofuran; hexane; water;
stirring (room temp., 7 h), hexane addn., filtering, evapn., S8 addn. and THF addn., stirring (30 min), NH4Cl aq. soln. addn.; extg. (hexane), concg., chromy. (SiO2, hexane); elem. anal.;
DOI:10.1021/om00010a007
- Guidance literature:
-
(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)dimethoxyborane;
With
lithium aluminium tetrahydride;
In
tetrahydrofuran;
at 20 ℃;
With
Cp2TiSe5;
In
tetrahydrofuran;
methyl iodide;
DOI:10.1016/S0040-4039(99)01036-9
