2,4,6-Tris[bis(trimethylsilyl)methyl]benzaldehyde

Base Information

• Chemical Name: 2,4,6-Tris[bis(trimethylsilyl)methyl]benzaldehyde
• CAS No.: 171620-65-8
• Molecular Formula: C28H60OSi6
• Molecular Weight: 581.297
• DSSTox Substance ID: DTXSID30570069
• Wikidata: Q82457392
• Mol file: 171620-65-8.mol

Synonyms:2,4,6-Tris[bis(trimethylsilyl)methyl]benzaldehyde;171620-65-8;DTXSID30570069

Chemical Property of 2,4,6-Tris[bis(trimethylsilyl)methyl]benzaldehyde

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 580.32597574
• Heavy Atom Count: 35
• Complexity: 625

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C(C1=CC(=C(C(=C1)C([Si](C)(C)C)[Si](C)(C)C)C=O)C([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

Technology Process of 2,4,6-Tris[bis(trimethylsilyl)methyl]benzaldehyde

There total 1 articles about 2,4,6-Tris[bis(trimethylsilyl)methyl]benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene (115160-05-9) + formic acid ethyl ester (109-94-4) → 2,4,6-trisbenzaldehyde (171620-65-8)

Guidance literature:

With tert.-butyl lithium;

DOI:10.1246/cl.1992.1599

Reference yield: 94.0%

2,4,6-trisbenzaldehyde (171620-65-8) → [2,4,6-Tris-(bis-trimethylsilanyl-methyl)-phenyl]-methanol

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at -78 - 20 ℃; for 16h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2021.122119

Reference yield: 94.0%

2,4,6-trisbenzaldehyde (171620-65-8) + toluene-4-sulfonic acid hydrazide (1576-35-8) → 2,4,6-trisbenzaldehyde tosylhydrazone (171620-66-9)

Guidance literature:

With boron trifluoride diethyl etherate; In ethanol; for 4h; Heating;

DOI:10.1246/bcsj.68.2757

upstream raw materials:

1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene

formic acid ethyl ester

Downstream raw materials:

2,4,6-trisbenzaldehyde tosylhydrazone

1,3,5-Tris-(bis-trimethylsilanyl-methyl)-2-diazomethyl-benzene

2,4,6-trisphenyloctathionane

2,4,6-trisphenylpentathiane