Germane, (1,1-dimethylethoxy)triethyl-

Base Information

• Chemical Name: Germane, (1,1-dimethylethoxy)triethyl-
• CAS No.: 18478-23-4
• Molecular Formula: C10H24GeO
• Molecular Weight: 232.89
• Mol file: 18478-23-4.mol

Synonyms:

Chemical Property of Germane, (1,1-dimethylethoxy)triethyl-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Germane, (1,1-dimethylethoxy)triethyl-

There total 3 articles about Germane, (1,1-dimethylethoxy)triethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert.-butylhydroperoxide (75-91-2) + tetrachloromethane (56-23-5) + Triethylgerman (1188-14-3) + aluminum tri-tert-butoxide (556-91-2) → triethylchlorogermane (994-28-5) + (tert-butoxy)triethylgermane (18478-23-4) + (tert-butylperoxy)triethylgermane (26452-74-4) + hexaethyldigermoxane (2538-70-7)

Guidance literature:

In tetrachloromethane; byproducts: O2, acetone, tert-butanol; under Ar; addn. of peroxide to soln. of aluminum and germanium compds. in CCl4, stirred at room temp. for 30 min; qualitative analysis, chromy. detection, iodometric titration;

DOI:10.1007/s11176-005-0375-y

Reference yield:

tert.-butylhydroperoxide (75-91-2) + di-tert-butyl diperoxyoxalate (1876-22-8) + Triethylgerman (1188-14-3) → (tert-butoxy)triethylgermane (18478-23-4) + (tert-butylperoxy)triethylgermane (26452-74-4)

Guidance literature:

In benzene; byproducts: CO2; (Ar); reacting germanium compd. with peroxides in benzene at 50°Cfor 1 h;

DOI:10.1007/s11176-005-0375-y

Reference yield:

titanium(IV) tetrabutoxide + tert.-butylhydroperoxide (75-91-2) + Triethylgerman (1188-14-3) → (tert-butoxy)triethylgermane (18478-23-4) + (tert-butylperoxy)triethylgermane (26452-74-4) + hexaethyldigermoxane (2538-70-7)

Guidance literature:

In benzene; byproducts: O2, tert-butanol; under Ar; peroxide and titanium and germanium compds. in benzene at 20°C;

DOI:10.1007/s11176-005-0375-y

upstream raw materials:

tert.-butylhydroperoxide

tetrachloromethane

Triethylgerman

aluminum tri-tert-butoxide

Refernces