Phenoxyacetic anhydride

Base Information

• Chemical Name: Phenoxyacetic anhydride
• CAS No.: 14316-61-1
• Molecular Formula: C16H14O5
• Molecular Weight: 286.284
• Hs Code.: 2918990090
• European Community (EC) Number: 627-222-6
• NSC Number: 259934
• DSSTox Substance ID: DTXSID30312648
• Nikkaji Number: J81.750C
• Wikidata: Q82063303
• Mol file: 14316-61-1.mol

Synonyms:Phenoxyacetic anhydride;14316-61-1;2-Phenoxyacetic anhydride;Acetic acid, phenoxy-, anhydride;(2-phenoxyacetyl) 2-phenoxyacetate;NSC 259934;PHENOXYACETICANHYDRIDE;Phenoxyacetc anhydrde;SCHEMBL264346;2-phenoxyacetyl 2-phenoxyacetate;DTXSID30312648;MFCD00059681;NSC259934;AKOS016009546;NSC-259934;AS-58486;Phenoxyacetic anhydride, >=97.0% (T);CS-0020049;FT-0742969;P0111;D91899;A855328;J-007754;J-523929

Chemical Property of Phenoxyacetic anhydride

Chemical Property:

• Vapor Pressure: 1.59E-07mmHg at 25°C
• Melting Point: 70-74 °C
• Refractive Index: 1.558
• Boiling Point: 427.823 °C at 760 mmHg
• Flash Point: 190.029 °C
• PSA: 61.83000
• Density: 1.234 g/cm³
• LogP: 2.21420
• Storage Temp.: Store at RT.
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 8
• Exact Mass: 286.08412354
• Heavy Atom Count: 21
• Complexity: 298

Purity/Quality:

99% ^*data from raw suppliers

Phenoxyacetic Anhydride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OCC(=O)OC(=O)COC2=CC=CC=C2

Technology Process of Phenoxyacetic anhydride

There total 5 articles about Phenoxyacetic anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-phenoxyacetic acid (122-59-8) → phenoxyacetic anhydride (14316-61-1)

Guidance literature:

With N,N-bis[2-oxo-3-oxazolidinyl]phosphorodiamidic chloride; triethylamine; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1055/s-1981-29544

Reference yield:

→ phenoxyacetic anhydride (14316-61-1)

Guidance literature:

With toluene; trichlorophosphate;

Reference yield:

→ phenoxyacetic anhydride (14316-61-1)

Guidance literature:

With toluene; trichlorophosphate;

upstream raw materials:

2-phenoxyacetic acid sodium salt

Phenoxyacetyl chloride

2-phenoxyacetic acid

Downstream raw materials:

phenoxy-acetic acid-[5-(4-nitro-phenoxy)-pentylamide]

Phenoxy-acetic acid (2R,3S,5R)-2-[bis-(4-methoxy-phenyl)-phenyl-methoxymethyl]-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-3-yl ester

3-methyl-2-(N-phenoxyacetylamino)-5-(2',3,',5'-tri-O-benzyl-β-D-ribofuranosyl)pyridine

N⁴-phenoxyacetylamino-1-(3,5-di-O-acetyl-2-deoxy-β-D-erythro-pentofuranosyl)-5-methylcytosine