Sodium phenoxyacetate

Base Information

• Chemical Name: Sodium phenoxyacetate
• CAS No.: 3598-16-1
• Molecular Formula: C8H7O3Na
• Molecular Weight: 174.132
• Hs Code.: 2918990090
• Mol file: 3598-16-1.mol

Synonyms:Aceticacid, phenoxy-, sodium salt (8CI,9CI);

Chemical Property of Sodium phenoxyacetate

Chemical Property:

• Vapor Pressure: 0Pa at 25℃
• Melting Point: 262-264 °C
• Boiling Point: 285 °C at 760 mmHg
• PKA: 3.17[at 20 ℃]
• Flash Point: 115.1 °C
• PSA: 49.36000
• Density: 1.498[at 20℃]
• LogP: -0.18470
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: 223.6g/L at 20℃

Purity/Quality:

99% ^*data from raw suppliers

Sodium Phenoxyacetate >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Sodium phenoxyacetate

There total 12 articles about Sodium phenoxyacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-Phenoxyethanol (122-99-6,56257-90-0,9004-78-8) → 2-phenoxyacetic acid sodium salt (3598-16-1)

Guidance literature:

With sodium hydroxide; oxygen; bismuth(III) nitrate; palladium on activated charcoal; at 90 ℃; for 1h;

Reference yield: 53.0%

2-Phenoxyethanol (122-99-6,56257-90-0,9004-78-8) → sodium phenoxide (139-02-6) + 2-phenoxyacetic acid sodium salt (3598-16-1)

Guidance literature:

With oxygen; bismuth(III) nitrate; palladium on activated charcoal; In sodium hydroxide; at 90 ℃; for 6h; Product distribution; also with coactivator and other activators, various times, reaction with other 2-phenoxyethanols;

Reference yield:

2-phenoxy-1-phenylethan-1-one oxime → benzamide (55-21-0,27208-38-4) + 2-phenoxyacetic acid sodium salt (3598-16-1) + aniline (62-53-3)

Guidance literature:

2-phenoxy-1-phenylethan-1-one oxime; With thionyl chloride; In acetonitrile; at 80 ℃; for 0.0333333h;

With sodium hydroxide; In ethanol; water; at 100 ℃; for 2h;

DOI:10.1039/c8gc00920a

upstream raw materials:

2-Phenoxyethanol

sodium monochloroacetic acid

phenol

chloroacetic acid

Downstream raw materials:

phenoxyacetic acid ethyl ester

phenoxyacetyl-2,3-epoxipropyl ester

2-phenoxy-1-phenylethanone

di(phenoxyacetato)phenylantimony(III)

Refernces

• 1、 Wang, Yinling,Du, Yiman,He, Jianghua,Zhang, Yuetao. "Transformation of lignin model compounds to: N -substituted aromatics via Beckmann rearrangement". supporting information. p. 3318 - 3326. Retrieved 2018/07/29.
• 2、 -. "A continuous synthesis of phenoxy acetic acid method". Paragraph 0022; 0023; 0024; 0026; 0027; 0028; 0030-0032. . Retrieved 2017/08/25.