Nonanoic anhydride

Base Information

• Chemical Name: Nonanoic anhydride
• CAS No.: 1680-36-0
• Molecular Formula: C18H34O3
• Molecular Weight: 298.466
• Hs Code.: 2915900090
• European Community (EC) Number: 216-854-4
• DSSTox Substance ID: DTXSID60168458
• Nikkaji Number: J195.324I
• Wikidata: Q83038068
• Mol file: 1680-36-0.mol

Synonyms:Nonanoic anhydride;1680-36-0;nonanoyl nonanoate;Pelargonic Anhydride;Nonan-1-oic anhydride;Nonanoic acid,1,1'-anhydride;NONANOICANHYDRIDE;EINECS 216-854-4;MFCD00057768;Nonanoic anhydride, ~98%;SCHEMBL2727904;Nonanoic acid, 1,1?-anhydride;DTXSID60168458;AKOS025396803;HY-W127390;BS-21699;CS-0185626;FT-0718337;P0957;D92047;J-010425

Chemical Property of Nonanoic anhydride

Chemical Property:

• Appearance/Colour: Clear yellow to orange oily liquid
• Vapor Pressure: 0.000121mmHg at 25°C
• Melting Point: 14.8 °C
• Refractive Index: 1.439-1.442
• Boiling Point: 335.3 °C at 760 mmHg
• Flash Point: 154.1 °C
• PSA: 43.37000
• Density: 0.914 g/cm³
• LogP: 5.55740
• Storage Temp.: −20°C
• XLogP3: 7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 16
• Exact Mass: 298.25079494
• Heavy Atom Count: 21
• Complexity: 235

Purity/Quality:

98%,99%, ^*data from raw suppliers

Nonanoic Anhydride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCCCCCCC(=O)OC(=O)CCCCCCCC
• Uses: Nonanoic anhydride is used in preparation of Diacyl Peroxides by peroxidation of Anhydrides in the presence of Aldehydes and Oxygen.

Technology Process of Nonanoic anhydride

There total 8 articles about Nonanoic anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

nonanoic acid (112-05-0) → nonanoic anhydride (1680-36-0)

Guidance literature:

With N,N-bis[2-oxo-3-oxazolidinyl]phosphorodiamidic chloride; triethylamine; In dichloromethane; at 20 ℃; for 0.75h;

DOI:10.1055/s-1981-29544

Reference yield: 73.0%

nonanoic acid (112-05-0) → Nonanoyl chloride (764-85-2) + nonanoic anhydride (1680-36-0)

Guidance literature:

With phosphorus trichloride; at 40 - 50 ℃; 4-5h;

DOI:10.1007/BF00960670

Reference yield: 57.0%

1-Iodooctane (629-27-6) + carbon monoxide (201230-82-2) + phenylboronic acid (98-80-6) → nonanoic anhydride (1680-36-0) + 1-phenylnonan-1-one (6008-36-2)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate; In water; benzene; at 20 ℃; for 16h; under 34202.3 Torr; Autoclave; Irradiation;

DOI:10.1021/ol401363t

upstream raw materials:

nonanoic acid

1-Heptene

acetic anhydride

1-Iodooctane

Downstream raw materials:

nonanamide

C₂₅H₃₉F₃N₂O₃

nonanonitrile

pyridine

Refernces

• 1、 Sumino, Shuhei,Ui, Takahito,Ryu, Ilhyong. "Synthesis of alkyl aryl ketones by Pd/light induced carbonylative cross-coupling of alkyl iodides and arylboronic acids". supporting information. p. 3142 - 3145. Retrieved 2013/07/26.
• 2、 Valitova, L. A.,Popova, E. V.,Ibragimov, Sh. N.,Ivanov, B. E.. "REACTION OF PHOSPHORUS TRICHLORIDE WITH CARBOXYLIC ACIDS". . p. 366 - 370. Retrieved 2007/10/02.