6008-36-2

Basic information

• Product Name: N-NONANOPHENONE
• Synonyms: 1-PHENYL-1-NONANONE;1-PHENYLNONAN-1-ONE;N-NONAPHENONE;N-NONANOPHENONE;N-OCTYL PHENYL KETONE;NONANOPHENONE;Nonanophenone,98%;n-Nonanophenone,98%
• CAS NO: 6008-36-2
• Molecular Formula: C₁₅H₂₂O
• Molecular Weight: 218.33
• EINECS: 227-861-7
• Mol File: 6008-36-2.mol
• Article Data: 77

Chemical Properties

• Melting Point: 14°C
• Boiling Point: 139-140°C 2mm
• Flash Point: 139-140°C/2mm
• Appearance: /
• Density: 0,94 g/cm3
• Vapor Pressure: 0.000563mmHg at 25°C
• Refractive Index: 1.5005-1.5025
• BRN: 2047454
• CAS DataBase Reference: N-NONANOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: N-NONANOPHENONE(6008-36-2)
• EPA Substance Registry System: N-NONANOPHENONE(6008-36-2)

Safety Data

• Safety Statements: 24/25
• Hazardous Substances Data: 6008-36-2(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID

Uses

Different sources of media describe the Uses of 6008-36-2 differently. You can refer to the following data:
1. N-NONANOPHENONE is used in the synthesis of novel alkylbenzene sulfonate gemini surfactants.
2. 1-Phenyl-1-nonanone is used in the synthesis of novel alkylbenzene sulfonate gemini surfactants.

Synthesis Reference(s)

The Journal of Organic Chemistry, 55, p. 788, 1990 DOI: 10.1021/jo00290a004Tetrahedron Letters, 37, p. 2197, 1996 DOI: 10.1016/0040-4039(96)00258-4

InChI:InChI=1/C15H22O/c1-2-3-4-5-6-10-13-15(16)14-11-8-7-9-12-14/h7-9,11-12H,2-6,10,13H2,1H3

Upstream product

• 143773-15-3 N-(t-butyl)-N,N-(1-phenyl-1-nonylidene)amine 
• 14047-60-0 sodium nonanoate 
• 23665-09-0 phenylzinc iodide 
• 65488-05-3 4-iodobutyrophenone 
• 14402-93-8 dipentylzinc 
• 17049-49-9 octylmagnesium bromide 
• 98-88-4 benzoyl chloride 
• 111-83-1 1-bromo-octane 
• 111-85-3 n-chlorooctane 
• 103687-22-5 ((CH₃)3C₆H₂)2BCHLiC₇H₁₅ 
• 100-52-7 benzaldehyde 
• 93-58-3 benzoic acid methyl ester 
• 629-05-0 n-octyne 
• 128993-33-9 1-benzyl-2-(1-hydroxy-1-phenylnonyl)-4,5-dihydroimidazole 

Downstream Products

• 92779-85-6 1-phenylnonan-1-amine 
• 4534-55-8 6-phenyltetradecane 
• 94681-77-3 6-Phenyl-n-tetradecen 
• 94760-89-1 n-Butyl-(p-n-nonylphenyl)-keton 
• 1233091-81-0 5-(4-octylphenyl)-1,3,4-thiadiazol-2-amine 
• 1369885-79-9 3-(2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethyl-N-(5-(4-octylphenyl)-1,3,4-thiadiazol-2-yl)cyclopropanecarboxamide 
• 10541-56-7 4-n-octylacetophenone 
• 2189-60-8 Octylbenzene 
• 3575-31-3 4-octylbenzoic acid 
• 1439374-22-7 α-(methanesulfonyloxy)octyl phenyl ketone 
• 1380541-61-6 (Z)-β-chloro-α-heptylcinnamonitrile 
• 1380541-60-5 (E)-β-chloro-α-heptylcinnamonitrile 
• 131320-85-9 (S)-(-)-1-phenyl-1-nonanol 
• 80155-20-0 4-(4-Nonyl-phenylazo)-phenol 

Relevant articles and documents

Preparation of Primary and Secondary Dialkylmagnesiums by a Radical I/Mg-Exchange Reaction Using sBu2Mg in Toluene

The treatment of primary or secondary alkyl iodides with sBu2Mg in toluene (25–40 °C, 2–4 h) provided dialkylmagnesiums that underwent various reactions with aldehydes, ketones, acid chlorides or allylic bromides. 3-Substituted secondary cyclohexyl iodides led to all-cis-3-cyclohexylmagnesium reagents under these exchange conditions in a highly stereoconvergent manner. Enantiomerically enriched 3-silyloxy-substituted secondary alkyl iodides gave after an exchange reaction with sBu2Mg stereodefined dialkylmagnesiums that after quenching with various electrophiles furnished various 1,3-stereodefined products including homo-aldol products (99 % dr and 98 % ee). Mechanistic studies confirmed a radical pathway for these new iodine/magnesium-exchange reactions.

LIGHT INDUCED CATALYTIC C-H OXYGENATION OF ALKANES

A method of oxygenating a benzylic C-H bond is provided. The method comprises light induced activation of an initiator and subsequent reaction with oxygen, resulting in the formation of free radicals. Subsequently, free radicals catalyze the reaction of the benzylic C-H bond with oxygen, thereby forming an oxygenated compound.

Ir(NHC)-Catalyzed Synthesis of β-Alkylated Alcohols via Borrowing Hydrogen Strategy: Influence of Bimetallic Structure

Multi N-heterocyclic carbene(NHC)-modified iridium catalysts were employed in the β-alkylation of alcohols; dimerization of primary alcohols (Guerbet reaction), cross-coupling of secondary and primary alcohols, and intramolecular cyclization of alcohols. Mechanistic studies of Guerbet reaction, including kinetic experiments, mass analysis, and density functional theory (DFT) calculation, were employed to explain the fast reaction promoted by bimetallic catalysts, and the dramatic reactivity increase of monometallic catalysts at the late stage of the reaction. (Figure presented.).