1,3,5-triazine-2,4,6-triyltrinitrilohexamethanol

Base Information

• Chemical Name: 1,3,5-triazine-2,4,6-triyltrinitrilohexamethanol
• CAS No.: 531-18-0
• Deprecated CAS: 1195264-09-5
• Molecular Formula: C9H18 N6 O6
• Molecular Weight: 306.279
• Hs Code.: 2933699090
• European Community (EC) Number: 208-503-9
• NSC Number: 118741
• UNII: QF209902UL
• DSSTox Substance ID: DTXSID1020693
• Nikkaji Number: J6.978G
• Wikidata: Q27287227
• Mol file: 531-18-0.mol

Synonyms:Methanol,(1,3,5-triazine-2,4,6-triyltrinitrilo)hexakis- (9CI); Methanol, (s-triazine-2,4,6-triyltrinitrilo)hexa-(6CI,7CI,8CI); 1,3,5-Triazine-2,4,6-triamine, hexakis(hydroxymethyl)-;2,4,6-Tris[di(hydroxymethyl)amino]-1,3,5-triazine; Cilag 61;Hexa(hydroxymethyl)melamine; Hexakis(hydroxymethyl)melamine;Hexamethylolmelamine; NSC 118741; Resloom M 75

Chemical Property of 1,3,5-triazine-2,4,6-triyltrinitrilohexamethanol

Chemical Property:

• Vapor Pressure: 8.21E-19mmHg at 25°C
• Melting Point: 150℃
• Refractive Index: 1.8120 (estimate)
• Boiling Point: 669°Cat760mmHg
• PKA: 12.05±0.10(Predicted)
• Flash Point: 358.4°C
• PSA: 169.77000
• Density: 1.821g/cm³
• LogP: -4.01040
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• XLogP3: -2.2
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 9
• Exact Mass: 306.12878232
• Heavy Atom Count: 21
• Complexity: 223

Purity/Quality:

98%min ^*data from raw suppliers

((1,3,5-Triazine-2,4,6-triyl)tris(azanetriyl))hexamethanol 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(N(CO)C1=NC(=NC(=N1)N(CO)CO)N(CO)CO)O
• Uses: In fireproofing and creaseproofing of cottons, rayons.

Technology Process of 1,3,5-triazine-2,4,6-triyltrinitrilohexamethanol

There total 3 articles about 1,3,5-triazine-2,4,6-triyltrinitrilohexamethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 2,4,6-triamino-s-triazine (108-78-1,25778-04-5,94977-27-2) → hexa(hydroxymethyl)melamine (531-18-0)

Guidance literature:

In water; pH=7.5; Heating;

DOI:10.1039/c7nj03578k

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 2,4,6-triamino-s-triazine (108-78-1,25778-04-5,94977-27-2) → [1,3,5]triazine-2,4,6-triyltriamino-tris-methanol (1017-56-7) + hexa(hydroxymethyl)melamine (531-18-0)

Guidance literature:

Reference yield:

→ hexa(hydroxymethyl)melamine (531-18-0)

Guidance literature:

Melamin, 6.5 mol Formaldehyd, 90grad;

DOI:10.1002/apmc.1976.050560102

upstream raw materials:

formaldehyd

2,4,6-triamino-s-triazine

Downstream raw materials:

N₂,N₂,N₄,N₄,N₆,N₆-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine

Refernces

• 1、 Wang, Mei,Song, Xianghai,Jiang, Jianchun,Xia, Jianling,Ding, Haiyang,Li, Mei. "Plasticization and thermal behavior of hydroxyl and nitrogen rich group-containing tung-oil-based ester plasticizers for PVC". . p. 2422 - 2431. Retrieved 2018/02/19.
• 2、 -. "LIQUID CRYSTAL ALIGNING AGENT, LIQUID CRYSTAL ALIGNMENT FILM, LIQUID CRYSTAL DISPLAY, COMPOUND, AND PROCESS FOR PRODUCING THE COMPOUND". Paragraph 0211-0212. . Retrieved 2020/11/25.