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531-18-0

Basic Information
CAS No.: 531-18-0
Name: 1,3,5-triazine-2,4,6-triyltrinitrilohexamethanol
Article Data: 17
Molecular Structure:
Molecular Structure of 531-18-0 (1,3,5-triazine-2,4,6-triyltrinitrilohexamethanol)
Formula: C9H18 N6 O6
Molecular Weight: 306.279
Synonyms: Methanol,(1,3,5-triazine-2,4,6-triyltrinitrilo)hexakis- (9CI); Methanol, (s-triazine-2,4,6-triyltrinitrilo)hexa-(6CI,7CI,8CI); 1,3,5-Triazine-2,4,6-triamine, hexakis(hydroxymethyl)-;2,4,6-Tris[di(hydroxymethyl)amino]-1,3,5-triazine; Cilag 61;Hexa(hydroxymethyl)melamine; Hexakis(hydroxymethyl)melamine;Hexamethylolmelamine; NSC 118741; Resloom M 75
Density: 1.821g/cm3
Melting Point: 150℃
Boiling Point: 669°Cat760mmHg
Flash Point: 358.4°C
Safety: A poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits toxic fumes of NOx.
PSA: 169.77000
LogP: -4.01040
Synthetic route
50-00-0

formaldehyd

108-78-1

2,4,6-triamino-s-triazine

531-18-0

hexa(hydroxymethyl)melamine

Conditions
ConditionsYield
In water pH=7.5; Heating;86%
With hydrogenchloride
With sodium hydroxide
50-00-0

formaldehyd

108-78-1

2,4,6-triamino-s-triazine

A

1017-56-7

[1,3,5]triazine-2,4,6-triyltriamino-tris-methanol

B

531-18-0

hexa(hydroxymethyl)melamine

60-33-3

linoleic acid

531-18-0

hexa(hydroxymethyl)melamine

hexa(linoleoylhydroxymethyl)melamine

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 24h; Inert atmosphere;95%
531-18-0

hexa(hydroxymethyl)melamine

35948-25-5

9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide

66499-32-9

N,N,N',N',N'',N''-Hexakis-(10-oxo-10H-9-oxa-10λ5-phospha-phenanthren-10-ylmethyl)-[1,3,5]triazine-2,4,6-triamine

Conditions
ConditionsYield
With benzenesulfonic acid at 165 - 240℃;89%
67-56-1

methanol

531-18-0

hexa(hydroxymethyl)melamine

3089-11-0

hexakis-N-methoxymethyl-[1,3,5]triazine-2,4,6-triamine

Conditions
ConditionsYield
With hydrogenchloride
With nitric acid In water at 45 - 55℃; for 1.5h; pH=1.5 - 3.8; Product distribution / selectivity;
With hydrogenchloride In water at 35℃; for 2h; pH=2.5; pH-value; Temperature;
531-18-0

hexa(hydroxymethyl)melamine

50693-84-0

hexakis-N-chloromethyl-[1,3,5]triazine-2,4,6-triamine

Conditions
ConditionsYield
With phosphorus trichloride In N,N-dimethyl-formamide at 0℃;
531-18-0

hexa(hydroxymethyl)melamine

75-57-0

tetramethlyammonium chloride

106-89-8

epichlorohydrin

71-36-3

butan-1-ol

Hexamethylolmelamineglycidyl Ether

Conditions
ConditionsYield
With sodium hydroxide In water
With sodium hydroxide In water
531-18-0

hexa(hydroxymethyl)melamine

C9H24N12

Conditions
ConditionsYield
With ammonia In methanol at 50 - 60℃; under 1140.08 Torr; for 2h; Inert atmosphere; Autoclave;
531-18-0

hexa(hydroxymethyl)melamine

111-42-2

2,2'-iminobis[ethanol]

1609117-63-6

C33H72N12O12

Conditions
ConditionsYield
In ethanol at 60 - 80℃; for 3h;
531-18-0

hexa(hydroxymethyl)melamine

111-42-2

2,2'-iminobis[ethanol]

C17H36N8O8

Conditions
ConditionsYield
In ethanol at 30 - 60℃; for 3h;
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Chemistry

IUPAC Name: [[4,6-Bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol
The MF of 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol (CAS NO.531-18-0) is C9H18N6O6.

                                 
The MW of 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol (CAS NO.531-18-0) is 306.27582.
Synonyms of 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol (CAS NO.531-18-0): Hexamethylolmelamine ; (1,3,5-Triazine-2,4,6-triyltrinitrilo)hexakismethanol ; Methanol, 1,1',1'',1''',1'''',1'''''-(1,3,5-triazine-2,4,6-triyltrinitrilo)hexakis- ; (s-Triazine-2,4,6-triyltrinitrilo)hexamethanol ; 1,3,5-Triazine-2,4,6-triamine, hexakis(hydroxymethyl)- ; 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol
Index of Refraction: 1.812  
EINECS: 208-503-9
Density: 1.821 g/ml 
Flash Point: 358.4 °C
Boiling Point: 669 °C

Toxicity Data With Reference

1.    

skn-rbt 20 mg/24H MOD

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,876.
2.    

eye-rbt 100 mg/24H MOD

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,154.
3.    

ivn-mus LD50:180 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#04006 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits toxic fumes of NOx.