Stannane, dichlorobis[(2-chlorophenyl)methyl]-

Base Information

• Chemical Name: Stannane, dichlorobis[(2-chlorophenyl)methyl]-
• CAS No.: 19135-39-8
• Molecular Formula: C14H12Cl4Sn
• Molecular Weight: 440.771
• Mol file: 19135-39-8.mol

Synonyms:

Chemical Property of Stannane, dichlorobis[(2-chlorophenyl)methyl]-

Chemical Property:

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Stannane, dichlorobis[(2-chlorophenyl)methyl]-

There total 1 articles about Stannane, dichlorobis[(2-chlorophenyl)methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

tin (7440-31-5) + 1-chloro-2-(chloromethyl)benzene (611-19-8) → di(o-chlorobenzyl)tin dichloride (19135-39-8)

Guidance literature:

With iodine; In water; toluene; for 5h; Reflux;

DOI:10.1016/j.bioorg.2019.103402

Reference yield: 92.0%

di(o-chlorobenzyl)tin dichloride (19135-39-8) + salicylaldehyde isonicotinoylhydrazone (495-84-1) → (o-ClphenylCH2)2Sn(salicylaldehyde isonicotinylhydrazone-2H)

Guidance literature:

With triethylamine; In benzene; byproducts: Et3N-HCl; Sn-contg. compd. (2.5 mmol) in benzene was added dropwise with stirring at room temp. into the flask contg. a ligand (2.5 mmol), triethylamine and benzene; stirring for 3 h; the ppt. of Et3N-HCl was filtered off, washed with benzene, and the filtrate was concd.; the solid was formed after addn. of petroleum ether (30-60°C); recrystn. from CH2Cl2/petroleum ether; elem. anal.;

DOI:10.1016/j.jorganchem.2005.04.049

Reference yield: 87.0%

(E)-4-chloro-N'-(2-hydroxy-4-methoxybenzylidene)benzohydrazide + di(o-chlorobenzyl)tin dichloride (19135-39-8) → [N-(4-methoxy-2-oxidobenzylidene)-4-chlorobenzyhydrazidato]di(o-chlorobenzyl)tin(IV)

Guidance literature:

In methanol; for 3.5h; Reflux;

DOI:10.1016/j.poly.2014.06.043

upstream raw materials:

tin

1-chloro-2-(chloromethyl)benzene

Downstream raw materials:

(CH₃)2Sn(C₆H₄-o-Cl)2

[Et₃NH][(2-Cl-C₆H₄CH₂)2SnCl₂(2-quinaldic acid(-1H))]

Refernces