4-NITROPHENYL ACRYLATE

Base Information

• Chemical Name: 4-NITROPHENYL ACRYLATE
• CAS No.: 2123-85-5
• Molecular Formula: C9H7 N O4
• Molecular Weight: 193.159
• Mol file: 2123-85-5.mol

Synonyms:Acrylicacid, p-nitrophenyl ester (7CI,8CI); 4-Nitrophenyl 2-propenoate; 4-Nitrophenylacrylate; NSC 144290; p-Nitrophenyl acrylate

Chemical Property of 4-NITROPHENYL ACRYLATE

Chemical Property:

• Vapor Pressure: 0.000124mmHg at 25°C
• Melting Point: 61°C
• Boiling Point: 334.9°Cat760mmHg
• Flash Point: 164.5°C
• PSA: 72.12000
• Density: 1.283g/cm³
• LogP: 2.20940

Purity/Quality:

99% ^*data from raw suppliers

4-Nitrophenylacrylate ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-NITROPHENYL ACRYLATE

There total 4 articles about 4-NITROPHENYL ACRYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + acryloyl chloride (814-68-6,25189-84-8) → p-nitrophenyl acrylate (2123-85-5)

Guidance literature:

With potassium hydroxide; In water; at 5 ℃;

DOI:10.1007/s10847-009-9711-x

Reference yield: 54.0%

4-nitro-phenol (100-02-7,78813-13-5,89830-32-0) + acrylic acid (79-10-7) → p-nitrophenyl acrylate (2123-85-5)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 25 ℃; for 18h;

DOI:10.1002/chem.200600627

Reference yield:

4'-nitrophenyl 3-bromopropionate (78939-58-9) → p-nitrophenyl acrylate (2123-85-5)

Guidance literature:

With sodium 3,4-dinitrophenoxide; In tetrahydrofuran; at 34.3 ℃; Rate constant;

DOI:10.1021/jo00164a017

upstream raw materials:

4-nitro-phenol

acryloyl chloride

4'-nitrophenyl 3-bromopropionate

acrylic acid

Downstream raw materials:

p-nitrophenyl 3-(benzyloxyamino)propanoate hydrochloride

(1R,2S,4S)-1,4,5,6,7,7-Hexabromo-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 4-nitro-phenyl ester

1,4,5,6-Tetrabromo-7,7-dimethoxy-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 4-nitro-phenyl ester

16,18-Dioxa-17-aza-tricyclo[10.6.0.0^13,17]octadecane-13,15-dicarboxylic acid 13-ethyl ester 15-(4-nitro-phenyl) ester

Refernces

• 1、 Barr, Lorna,Lincoln, Stephen F.,Easton, Christopher J.. "Reversal of regioselectivity and enhancement of rates of nitrile oxide cycloadditions through transient attachment of dipolarophiles to cyclodextrins". . p. 8571 - 8580. Retrieved 2006.
• 2、 Liu, Zi,Wu, Wan-Xia. "Novozym 435-Catalyzed Synthesis of Well-Defined Hyperbranched Aliphatic Poly(β-thioether ester)". . . Retrieved 2020/02/18.