3-(Tris(trimethylsiloxy)silyl)propyl methacrylate

Base Information

• Chemical Name: 3-(Tris(trimethylsiloxy)silyl)propyl methacrylate
• CAS No.: 17096-07-0
• Molecular Formula: C16H38O5Si4
• Molecular Weight: 422.817
• Hs Code.: 29319090
• European Community (EC) Number: 241-165-0
• UNII: D32S78J7T8
• DSSTox Substance ID: DTXSID00168977
• Nikkaji Number: J138.329I
• Wikidata: Q27276023
• Mol file: 17096-07-0.mol

Synonyms:17096-07-0;3-(METHACRYLOYLOXY)PROPYLTRIS(TRIMETHYLSILOXY)SILANE;3-(1,1,1,5,5,5-Hexamethyl-3-((trimethylsilyl)oxy)trisiloxan-3-yl)propyl methacrylate;3-[Tris(trimethylsiloxy)silyl]propyl methacrylate;3-(tris(trimethylsiloxy)silyl)propyl methacrylate;3-tris(trimethylsilyloxy)silylpropyl 2-methylprop-2-enoate;UNII-D32S78J7T8;D32S78J7T8;EINECS 241-165-0;3-[Tris(trimethylsilyloxy)silyl]propyl Methacrylate;SILAPLANE-TM 0701T;methacryloxypropyltris(trimethylsiloxy)silane;3-Methacryloxypropyltris(trimethylsiloxy)silane;S-503TS;3-(3,3,3-Trimethyl-1,1-bis((trimethylsilyl)oxy)disiloxanyl)propyl methacrylate;SIM-6487.6;KF-2801;SK-5001;X-22-2404;X-22-5002;MFCD00053871;2-PROPENOIC ACID, 2-METHYL-, 3-(3,3,3-TRIMETHYL-1,1-BIS((TRIMETHYLSILYL)OXY)-1-DISILOXANYL)PROPYL ESTER;Tris(trimethylsiloxy)-3-methacryloxypropylsilane;(3-methacryloxypropyl)tris(trimethylsiloxy)silane;(3-methacryloyloxypropyl) tris (trimethylsiloxy) silane;3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate;Propyltris(Trimethylsiloxy;SCHEMBL35807;C16H38O5Si4;BESKSSIEODQWBP-UHFFFAOYSA-;DTXSID00168977;C16-H38-O5-Si4;AKOS015903752;FS-5084;tris(trimethylsiloxy)silylpropyl methacrylate;CS-0006230;FT-0615959;M1324;methacryloxypropyltris(trimethyl-siloxy)silane;D84157;3-methacryloxypropyl tris (trimethylsiloxy) silane;A847351;Tris(trimethylsiloxy)-3-(methacryloxy)propylsilane;3-(Methacryloyloxypropyl)Tris(Trimethylsiloxy)Silane;3-[tris(trimethylsilyloxy)silyl] propyl methacrylate;gamma-Methacryloxypropyl-tris (trimethylsiloxy)silane;J-010673;3-(Methacryloyloxy)propyltris(trimethylsilyloxy)silane;Q27276023;Tris(trimethylsiloxy)-3-methacryloxypropylsilane <4% Dimer;Methacrylic Acid 3-[Tris(trimethylsilyloxy)silyl]propyl Ester;3-[Tris(trimethylsilyloxy)silyl]propyl Methacrylate (stabilized with MEHQ);3-(1,1,1,5,5,5-Hexamethyl-3-((trimethylsilyl)oxy)trisiloxan-3-yl)propylmethacrylate;3-[Tris(trimethylsiloxy)silyl]propyl methacrylate, contains MEHQ + HQ as stabilizer, 98%;2-Propenoic acid, 2-methyl-, 3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl ester;3-{2,2,6,6-tetramethyl-4-[(trimethylsilyl)oxy]-3,5-dioxa-2,4,6-trisilaheptan-4-yl}propyl 2-methylprop-2-enoate

Chemical Property of 3-(Tris(trimethylsiloxy)silyl)propyl methacrylate

Chemical Property:

• Appearance/Colour: Colorless transparent liquid
• Vapor Pressure: <1 mm Hg ( 20 °C)
• Melting Point: <0 °C
• Refractive Index: n20/D 1.419(lit.)
• Boiling Point: 368.6 °C at 760 mmHg
• Flash Point: 146.9 °C
• PSA: 53.99000
• Density: 0.933 g/cm³
• LogP: 4.98920
• Storage Temp.: below 5° C
• Water Solubility.: Immiscible with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 12
• Exact Mass: 422.17963045
• Heavy Atom Count: 25
• Complexity: 420

Purity/Quality:

98% ^*data from raw suppliers

3-(Methacryloyloxy)propyltris(trimethylsiloxy)silane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=C)C(=O)OCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C
• Uses: 3-(Methacryloyloxy)propyltris(trimethylsiloxy) silane acts as a tetramethylsilane-protected silicate compound utilized for proteomics research. It is also used as a silane coupling agent, silane adhesion promoter, silane hydrophobing agent, silane dispersing agent and silane crosslinking agent. It is also employed as a silane moisture scavenger, polypropylene catalyst, silicate stabilizer, polyurethane endcapper silane, silane drying agent, silane curing agent and silane reinforcer. Further, it serves as a silylating agent, silane reducing agent, silyl building block and synthons in synthetic chemistry.

Technology Process of 3-(Tris(trimethylsiloxy)silyl)propyl methacrylate

There total 5 articles about 3-(Tris(trimethylsiloxy)silyl)propyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.7%

trimethylsilyl acetate (2754-27-0) + [3-(methacryloyloxy)propyl]trimethoxysilane (2530-85-0) → 3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate (17096-07-0)

Guidance literature:

With trifluorormethanesulfonic acid; 2,6-di-tert-butyl-4-methyl-phenol; at 80 ℃; for 1h; Dean-Stark; Inert atmosphere;

Reference yield: 93.1%

Hexamethyldisiloxane (107-46-0) + [3-(methacryloyloxy)propyl]trimethoxysilane (2530-85-0) → 3-MAPSi(OMe)(OSiMe3)2 + 3-MAPSi(OH)(OSiMe3)2 (83692-44-8) + 3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate (17096-07-0)

Guidance literature:

Hexamethyldisiloxane; With methanol; sulfuric acid; at 5 - 10 ℃; for 1h;

[3-(methacryloyloxy)propyl]trimethoxysilane; at 5 - 10 ℃; for 1.5h;

With sulfuric acid; water; more than 3 stages;

Reference yield: 83.0%

Hexamethyldisiloxane (107-46-0) + [3-(methacryloyloxy)propyl]trimethoxysilane (2530-85-0) → 3-[3,3,3-trimethyl-1,1-bis[(trimethylsilyl)oxy]disiloxanyl]propyl methacrylate (17096-07-0)

Guidance literature:

Hexamethyldisiloxane; [3-(methacryloyloxy)propyl]trimethoxysilane; With sulfuric acid; acetic acid; trifluorormethanesulfonic acid; at -15 - 20 ℃;

With 1,1,1,3,3,3-hexamethyl-disilazane; at 20 ℃; for 2h; Product distribution / selectivity;

upstream raw materials:

chloro-trimethyl-silane

[3-(methacryloyloxy)propyl]trimethoxysilane

Hexamethyldisiloxane

trimethylsilyl acetate