(σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0)

Base Information

• Chemical Name: (σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0)
• CAS No.: 701913-42-0
• Molecular Formula: C₃₂H₁₄F₁₂N₂O₃Pt
• Molecular Weight: 897.536
• Mol file: 701913-42-0.mol

Synonyms:(σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0)

Chemical Property of (σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0)

There total 2 articles about (σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

maleic anhydride (108-31-6) + tris(norbornene)platinum(0) (57158-98-2) + N,N'-bis(bis(3,5-trifluoromethyl)phenyl)acenaphthenequinonediimine (226071-21-2) → (σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0) (701913-42-0)

Guidance literature:

In tetrahydrofuran; (N2); dissolving platinum complex and ligands in THF, react at 21°C for 5 d; evapn., dissolving in CH2Cl2, addn. of pentane, decantation, washing with pentane, drying in vac.; elem. anal.;

DOI:10.1021/ja052729j

Reference yield: 43.0%

maleic anhydride (108-31-6) + tris(bicyclo[2.2.1]heptene)platinum(0) + N,N'-bis(bis(3,5-trifluoromethyl)phenyl)acenaphthenequinonediimine (226071-21-2) → (σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0) (701913-42-0)

Guidance literature:

In tetrahydrofuran; N2, to a soln. of alkene added at 0°C a Pt compd., stirred for 15min, imine added, stirred at 0°C for 45 min, heated to room temp .; evapd. to dryness, dissolved (CH2Cl2), added pentane, solvent removed, ppt. washed (pentane), org. phases combined, allowed to stand, ppt. washed (pentane), dried (vac.); elem. anal.;

DOI:10.1002/ejic.200300088

Reference yield: 85.0%

4-Octyne (1942-45-6) + (σ-N,σ-N'-bis(3,5-bis(trifluoromethyl)phenylimino)acenaphthene)(η2-maleic anhydride)platinum(0) (701913-42-0) + hydrogen (1333-74-0) → [(m,m'-(CF3)2C6H3)-bis(imino)acenaphthene]platina-2,3,4,5-tetra(propyl)cyclopentadiene (870525-20-5)

Guidance literature:

In tetrahydrofuran; (N2) addn. of platinum complex to a soln. of alkyne in THF, addn. of H2 for 3 min, heating to 60°C for 60 min, cooling to room temp.; evapn., addn. of pentane, sepn., drying ppt. in vac.;

DOI:10.1021/ja052729j

upstream raw materials:

maleic anhydride

N,N'-bis(bis(3,5-trifluoromethyl)phenyl)acenaphthenequinonediimine

tris(norbornene)platinum⁽⁰⁾

Downstream raw materials:

[(m,m'-(CF₃)2C₆H₃)-bis(imino)acenaphthene]platina-2,3,4,5-tetra(propyl)cyclopentadiene