Mercury, bis[tris(1-methylethyl)germyl]-

Base Information

• Chemical Name: Mercury, bis[tris(1-methylethyl)germyl]-
• CAS No.: 24004-54-4
• Molecular Formula: C18H42Ge2Hg
• Molecular Weight: 604.301
• Mol file: 24004-54-4.mol

Synonyms:

Chemical Property of Mercury, bis[tris(1-methylethyl)germyl]-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Mercury, bis[tris(1-methylethyl)germyl]-

There total 2 articles about Mercury, bis[tris(1-methylethyl)germyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

sodium dicarbonyl(cyclopentadienyl)ferrate + triisopropylgermylmercuric bromide (105260-39-7) → {(η-cyclopentadienyl)Fe(CO)2}2Hg + bis(triisopropylgermyl)mercury (24004-54-4) + sodium bromide (7647-15-6)

Guidance literature:

In tetrahydrofuran; hexane; addn. of Na-compound (prepared from (C5H5)Fe(CO)3 and excess 3% Na-amalgam) in THF to i-Pr3GeHgBr (prepared from (i-PrGe)2Hg and Br2) in hexane at -40°C; pptn. (NaBr), replacing of solvents in the mother-liquor by hexane, pptn. of Fe-compound, isolation of (i-Pr3Ge)2Hg by fractionation of the soln. in vac.;

DOI:10.1007/BF00956683

Reference yield: 56.5%

triisopropylgermyllithium (43106-46-3) + [Fe(η-cyclopentadienyl)(CO)2(HgBr)] → {(η-cyclopentadienyl)Fe(CO)2}2Hg + bis(triisopropylgermyl)mercury (24004-54-4) + mercury + lithium bromide (7550-35-8)

Guidance literature:

In toluene; addn. of Li-compound in toluene at -30°C to Fe-compound in toluene, after 0.5h the temp. was raised to 20°-C; separation of Hg, removal of solvent in vac., addn. of hexane to the residue, pptn., removal of LiBr by washing with H2O;

DOI:10.1007/BF00956683

Reference yield: 84.0%

chloro(cyclopentadienyl)(triphenylphosphine)nickel(II) + bis(triisopropylgermyl)mercury (24004-54-4) → {π-CpNi(PPh3)}2Hg + triisopropylchlorogermane (2816-54-8) + mercury

Guidance literature:

In hexane; toluene; reaction in evacuated ampul; slow addn. of (i-propyl3Ge)2Hg (in toluene) to toluenic soln. Ni-compound (20°C); left for 2 h; soln. becomes orange and pptn. of Hg; replacement of toluene by hexane;;

DOI:10.1007/BF00962028

upstream raw materials:

triisopropylgermyllithium

triisopropylgermylmercuric bromide

Downstream raw materials:

triisopropylchlorogermane

1-triisopropylgermyloxy-2-(triisopropylgermylmercurioxy)-3,5-di-tert-butylbenzene