3,3'-(1,2-Phenylene)bis[(E)-propenoic acid ethyl] ester

Base Information

Chemical Name:3,3'-(1,2-Phenylene)bis[(E)-propenoic acid ethyl] ester
CAS No.:28839-73-8
Molecular Formula:C16H18O4
Molecular Weight:274.317
Hs Code.:
DSSTox Substance ID:DTXSID301188440
Nikkaji Number:J1.574.028K

Synonyms:DTXSID301188440;3,3'-(1,2-Phenylene)bis[(E)-propenoic acid ethyl] ester;1,1'-Diethyl (2E,2'E)-3,3'-(1,2-phenylene)bis[2-propenoate];28839-73-8

Suppliers and Price of 3,3'-(1,2-Phenylene)bis[(E)-propenoic acid ethyl] ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3,3'-(1,2-Phenylene)bis[(E)-propenoic acid ethyl] ester

Chemical Property:

XLogP3:3.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:8
Exact Mass:274.12050905
Heavy Atom Count:20
Complexity:335

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCOC(=O)C=CC1=CC=CC=C1C=CC(=O)OCC
Isomeric SMILES:CCOC(=O)/C=C/C1=CC=CC=C1/C=C/C(=O)OCC

Technology Process of 3,3'-(1,2-Phenylene)bis[(E)-propenoic acid ethyl] ester

There total 8 articles about 3,3'-(1,2-Phenylene)bis[(E)-propenoic acid ethyl] ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 91047-77-7
ethyl (2E)-3-(2-bromophenyl)prop-2-enoate

: 140-88-5,9003-32-1
ethyl acrylate

: 28839-73-8
(E)-3-[2-{(E)-2-ethoxycarbonylvinyl}phenyl]acrylic acid ethyl ester

Guidance literature:: With Pd(OAc)2[P(2-tolyl)3]2; sodium acetate; In N,N-dimethyl-formamide; at 130 ℃; for 6h;
DOI:10.1016/0022-328X(84)80097-2

Reference yield: 84.0%

: 1099-45-2
ethyl (triphenylphosphoranylidene)acetate

: 643-79-8
o-phthalic dicarboxaldehyde

: 28839-73-8
(E)-3-[2-{(E)-2-ethoxycarbonylvinyl}phenyl]acrylic acid ethyl ester

Guidance literature:: In chloroform; at 20 ℃; for 16h; Inert atmosphere;
DOI:10.1021/ol901560r

Reference yield: 73.0%

: 105-36-2
ethyl bromoacetate

: 643-79-8
o-phthalic dicarboxaldehyde

: 28839-73-8
(E)-3-[2-{(E)-2-ethoxycarbonylvinyl}phenyl]acrylic acid ethyl ester

Guidance literature:: ethyl bromoacetate; With tributylphosphine; In tetrahydrofuran; at 0 ℃; for 0.0833333h;

o-phthalic dicarboxaldehyde; With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 2.5h; diastereoselective reaction;
DOI:10.1080/00397910802654633