(2,3-diphenyl-2-cyclopropen-1-yl)(phenyl)methanone

Base Information

• Chemical Name: (2,3-diphenyl-2-cyclopropen-1-yl)(phenyl)methanone
• CAS No.: 2892-41-3
• Molecular Formula: C22H16O
• Molecular Weight: 296.36200
• Mol file: 2892-41-3.mol

Synonyms:3-Benzoyl-1,2-diphenylcycloprop-1-en;3-Benzoyl-1,2-diphenylcyclopropen;1,2-Diphenyl-3-benzoyl-cyclopropen;3-Benzoyl-1,2-diphenyl-1-cyclopropen;

Chemical Property of (2,3-diphenyl-2-cyclopropen-1-yl)(phenyl)methanone

Chemical Property:

• PSA: 17.07000
• LogP: 5.11010

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (2,3-diphenyl-2-cyclopropen-1-yl)(phenyl)methanone

There total 9 articles about (2,3-diphenyl-2-cyclopropen-1-yl)(phenyl)methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

C8H6F4O2S + benzalacetophenone (94-41-7) → 1-Benzoyl-2,3-diphenyl-cycloprop-2-en (2892-41-3)

Guidance literature:

With lithium hexamethyldisilazane; In tetrahydrofuran; at -50 - 20 ℃; for 2.66667h; Inert atmosphere;

DOI:10.1002/chem.202104364

Reference yield:

acetophenone (98-86-2) → 1-Benzoyl-2,3-diphenyl-cycloprop-2-en (2892-41-3)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydroxide / ethanol / 0.08 h / 20 °C

2: lithium hexamethyldisilazane / tetrahydrofuran / 2.67 h / -50 - 20 °C / Inert atmosphere

With sodium hydroxide; lithium hexamethyldisilazane; In tetrahydrofuran; ethanol;

DOI:10.1002/chem.202104364

Reference yield:

benzaldehyde (100-52-7) → 1-Benzoyl-2,3-diphenyl-cycloprop-2-en (2892-41-3)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium hydroxide / ethanol / 0.08 h / 20 °C

2: lithium hexamethyldisilazane / tetrahydrofuran / 2.67 h / -50 - 20 °C / Inert atmosphere

With sodium hydroxide; lithium hexamethyldisilazane; In tetrahydrofuran; ethanol;

DOI:10.1002/chem.202104364

upstream raw materials:

2,3-diphenylcycloprop-2-enecarboxylic acid

2,3-diphenyl-2-cyclopropene-1-carbonyl chloride

diphenyl cadmium

acetophenone

Downstream raw materials:

(2,3-diphenylcycloallyl)(phenyl)methanol

tribenzoylmethane

cis-2,3-Diphenyl-cis-1-benzoyl-cyclopropan

cis-2,3-diphenyl-1-benzoylcyclopropane