Technology Process of Acetic acid, 2,2,2-trifluoro-, thallium(3+) salt (3:1)
There total 2 articles about Acetic acid, 2,2,2-trifluoro-, thallium(3+) salt (3:1) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
lithium trifluoroacetate;
In
trifluoroacetic acid;
byproducts: CF3COOH; solns. of Tl(OCOCF3)3, arene, and CF3COOLi in degassed CF3COOH were mixed at 25°C under Ar in the dark, mixt. was stirred for 1-3 h; rate const. is given; reaction was quenched with aq. KI, extd. with CH2Cl2, resulting ester was identified by gas chromy., (1)H NMR and mass spectra;
Kinetics;
DOI:10.1021/ja00335a039
- Guidance literature:
-
In
benzene;
byproducts: C6H5C6H5, N2, H2O; (Ar); stirring (2 h); pptn., evapn.; elem. anal.;
DOI:10.1007/BF02495221
