Methanimidamide, N,N'-bis(4-bromophenyl)-

Base Information

• Chemical Name: Methanimidamide, N,N'-bis(4-bromophenyl)-
• CAS No.: 30881-03-9
• Molecular Formula: C₁₃H₁₀Br₂N₂
• Molecular Weight: 354.044
• Mol file: 30881-03-9.mol

Synonyms:N-N'-Di-<4-brom-phenyl>-formamidin;N-N'-Di--formamidin;

Chemical Property of Methanimidamide, N,N'-bis(4-bromophenyl)-

Chemical Property:

• PSA: 24.39000
• LogP: 5.05650

Purity/Quality:

N,N'-BIS(4-BROMOPHENYL)FORMAMIDINE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanimidamide, N,N'-bis(4-bromophenyl)-

There total 4 articles about Methanimidamide, N,N'-bis(4-bromophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.1%

acetic acid (64-19-7,77671-22-8) + 4-bromo-aniline (106-40-1) → N,N'-bis-(4-bromophenyl)formamidine (30881-03-9,148651-27-8)

Guidance literature:

With orthoformic acid triethyl ester; at 140 ℃; for 24h;

DOI:10.1021/acs.joc.8b00151

Reference yield: 95.0%

orthoformic acid triethyl ester (122-51-0) + 4-bromo-aniline (106-40-1) → N,N'-bis-(4-bromophenyl)formamidine (30881-03-9,148651-27-8)

Guidance literature:

With [1-methyl-3-(trimethoxysilylpropyl)imidazolium]FeCl₄-functionalized mesoporous silica nanoparticles; In neat (no solvent); at 80 ℃; for 0.0833333h; Green chemistry;

DOI:10.1002/aoc.3800

Reference yield: 90.0%

4-bromo-aniline (106-40-1) + trimethyl orthoformate (149-73-5) → N,N'-bis-(4-bromophenyl)formamidine (30881-03-9,148651-27-8)

Guidance literature:

With 1,1,1,3',3',3'-hexafluoro-propanol; at 20 ℃; for 3h; chemoselective reaction;

DOI:10.1016/j.jfluchem.2010.10.002

upstream raw materials:

orthoformic acid triethyl ester

4-bromo-aniline

trimethyl orthoformate

acetic acid

Downstream raw materials:

4-(4-bromo-anilinomethylene)-2,5-diphenyl-2,4-dihydro-pyrazol-3-one

2-acetyl-3-(4-bromo-anilino)-acrylic acid ethyl ester

2-acetyl-3-(4-bromo-anilino)-acrylic acid-(4-bromo-anilide)

ethyl 3-((4-bromophenyl)amino)-2-cyanoacrylate