9H-Carbazole-9-carbonitrile

Base Information

• Chemical Name: 9H-Carbazole-9-carbonitrile
• CAS No.: 31892-44-1
• Molecular Formula: C13H8N2
• Molecular Weight: 192.22
• DSSTox Substance ID: DTXSID10503971
• Nikkaji Number: J1.812.225A
• Wikidata: Q82358134
• Mol file: 31892-44-1.mol

Synonyms:9H-Carbazole-9-carbonitrile;31892-44-1;Carbazole-9-carbonitrile;n-cyanocarbazole;SCHEMBL3890065;DTXSID10503971

Chemical Property of 9H-Carbazole-9-carbonitrile

Chemical Property:

• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 192.068748264
• Heavy Atom Count: 15
• Complexity: 268

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=CC=CC=C3N2C#N

Technology Process of 9H-Carbazole-9-carbonitrile

There total 8 articles about 9H-Carbazole-9-carbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrachloromethane (56-23-5) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 9-cyanocarbazole (31892-44-1) + bis-(9H-carbazol-9-yl) (1914-12-1) + 9-(9H-carbazol-3-yl)-9H-carbazole (18628-07-4) + 3,9-di-(N-carbazyl)carbazole (6515-02-2) + N-cyano-3-(N-carbazyl)carbazole (83415-87-6)

Guidance literature:

With ammonia; Mechanism; Product distribution; Irradiation; irradiation was performed in a carbazole-CCl₄ solution saturated with NH₃ gas;

DOI:10.1139/v82-353

Reference yield:

tetrachloromethane (56-23-5) + N-ethylcarbazole (86-28-2) → 9-cyanocarbazole (31892-44-1) + 9H-carbazole-1-carbonitrile (83415-88-7) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) + N-(α-trichloromethylvinyl)carbazole (98786-14-2)

Guidance literature:

With ammonia; for 0.5h; Irradiation;

Reference yield:

tetrachloromethane (56-23-5) + N-ethylcarbazole (86-28-2) → 9-cyanocarbazole (31892-44-1) + (9H)-carbazole-3-carbonitrile (57102-93-9) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) + N-(α-trichloromethylvinyl)carbazole (98786-14-2)

Guidance literature:

With ammonia; for 0.5h; Irradiation;

upstream raw materials:

tetrachloromethane

N-ethylcarbazole

9H-carbazole

9-Chloroacridine

Downstream raw materials:

2-(9-carbazolyl)-4-<(2,5-dimethoxyphenyl)methyl>-5-propyl-oxazole