2H-Azirine-3-carboxylic acid, phenylmethyl ester

Base Information

Chemical Name:2H-Azirine-3-carboxylic acid, phenylmethyl ester
CAS No.:328119-58-0
Molecular Formula:C10H9NO2
Molecular Weight:175.187
Hs Code.:
DSSTox Substance ID:DTXSID60458280
Nikkaji Number:J1.455.294D

Synonyms:benzyl 2H-azirine-3-carboxylate;328119-58-0;2H-Azirine-3-carboxylic acid, phenylmethyl ester;DTXSID60458280;3H-Azirine-2-carboxylic acid benzyl ester

Suppliers and Price of 2H-Azirine-3-carboxylic acid, phenylmethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 2H-Azirine-3-carboxylic acid, phenylmethyl ester

Chemical Property:

XLogP3:1.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:175.063328530
Heavy Atom Count:13
Complexity:229

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1C(=N1)C(=O)OCC2=CC=CC=C2

Technology Process of 2H-Azirine-3-carboxylic acid, phenylmethyl ester

There total 3 articles about 2H-Azirine-3-carboxylic acid, phenylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 328119-67-1
2-azidoacrylic acid benzyl ester

: 328119-58-0
Benzyl 2H-azirine-3-carboxylate

Guidance literature:: In dichloromethane; at 150 ℃; for 0.333333h;
DOI:10.1016/S0040-4039(03)01205-X

Reference yield:

: 10288-11-6
Benzyl 2,3-dibromopropionate

: 328119-58-0
Benzyl 2H-azirine-3-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / NaN₃ / dimethylformamide / 0.13 h / 65 °C

2: toluene / 10 h / 105 °C

With sodium azide; In N,N-dimethyl-formamide; toluene; 1: Elimination / 2: Cyclization;

Reference yield:

: 2495-35-4,25036-21-9
benzylacrylate

: 328119-58-0
Benzyl 2H-azirine-3-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 98 percent / Br₂ / CH₂Cl₂

2: 95 percent / NaN₃ / dimethylformamide / 0.13 h / 65 °C

3: toluene / 10 h / 105 °C

With sodium azide; bromine; In dichloromethane; N,N-dimethyl-formamide; toluene; 1: Bromination / 2: Elimination / 3: Cyclization;