Tri-tert-butyl(methyl)stannane

Base Information

Chemical Name:Tri-tert-butyl(methyl)stannane
CAS No.:35569-12-1
Molecular Formula:C13H30Sn
Molecular Weight:305.091
Hs Code.:
DSSTox Substance ID:DTXSID30547312
Wikidata:Q82425452

Synonyms:Tri-tert-butyl(methyl)stannane;35569-12-1;DTXSID30547312

Suppliers and Price of Tri-tert-butyl(methyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Tri-tert-butyl(methyl)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:306.136954
Heavy Atom Count:14
Complexity:159

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Sn](C)(C(C)(C)C)C(C)(C)C

Technology Process of Tri-tert-butyl(methyl)stannane

There total 2 articles about Tri-tert-butyl(methyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 107879-74-3
(CH₃)Sn(C(CH₃)3)2I

: 677-22-5
tert-butylmagnesium chloride

: 35569-11-0
di(t-butyl)dimethylstannane

: 35569-12-1
(tert-C₄H₉)3SnCH₃

Guidance literature:: With CH₃MgI; In diethyl ether; a soln. of Me(t-Bu)2SnI in ether is added to a soln. of tert-butylchloromagnesium in ether; boiling for 13 h;; removal of solvent; rectification; the fraction obtained at 95-106°C (10 mm) is added to CH3MgI in ether; mixt. is boiled for 3 h; rectification;;

Reference yield: 72.0%

: 54031-00-4
1-bromo-2-((trimethylstannyl)methyl)benzene

: 1529-47-1
chlorotrimethylgermane

: 1-(trimethylgermyl)-2-((tert-butyldimethylstannyl)methyl)benzene

: 113419-98-0
1-trimethylgermyl-2-trimethylgermylmethylbenzene

: 35569-11-0
di(t-butyl)dimethylstannane

: 3531-47-3
(t-butyl)trimethylstannane

: 35569-12-1
(tert-C₄H₉)3SnCH₃

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; pentane; Ar atmosphere; cooling soln. of t-BuLi in pentane and THF (-80°C), addn. of Sn-compd., stirring (60 min, -80°C), quenching with Me3GeCl; hydrolysation (aq. NH4Cl), diln. (Et2O), sepn. of org. layer, washing (H2O), drying (MgSO4), evapn.;