T-BUTYL TRIFLUOROACETATE

Base Information

• Chemical Name: T-BUTYL TRIFLUOROACETATE
• CAS No.: 400-52-2
• Molecular Formula: C6H9 F3 O2
• Molecular Weight: 170.131
• Hs Code.: 2915900090
• Mol file: 400-52-2.mol

Synonyms:Aceticacid, trifluoro-, 1,1-dimethylethyl ester (9CI); Acetic acid, trifluoro-,tert-butyl ester (6CI,7CI,8CI); Trifluoroacetic acid tert-butyl ester;tert-Butyl trifluoroacetate

Chemical Property of T-BUTYL TRIFLUOROACETATE

Chemical Property:

• Vapor Pressure: 76.8mmHg at 25°C
• Refractive Index: 1.3300
• Boiling Point: 83°Cat760mmHg
• Flash Point: °C
• PSA: 26.30000
• Density: 1.153g/cm³
• LogP: 1.89040

Purity/Quality:

98%Min ^*data from raw suppliers

t-Butyltrifluoroacetate 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F

MSDS Files:

SDS file from LookChem

Useful:

• Uses: t-Butyl trifluoroacetate is used in the method of producing elastic fluorohydrocarbon resin.

Technology Process of T-BUTYL TRIFLUOROACETATE

There total 8 articles about T-BUTYL TRIFLUOROACETATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

tertiary butyl chloride (507-20-0) + bis-[(trifluoroacetoxy)iodo]benzene (2712-78-9) → iodobenzene (591-50-4) + tert-butyl trifluoroacetate (400-52-2) + para-diiodobenzene (624-38-4,1032416-46-8) + (Dichloroiodo)benzene (932-72-9)

Guidance literature:

In chloroform;

Reference yield: 40.0%

2,4,6,2',4',6'-hexa-tert-butyl-4,4'-peroxy-bis-cyclohexa-2,5-dienone (1975-14-0) → tert-butyl trifluoroacetate (400-52-2) + 2,6-di-tert-butyl-4-hydroxyphenol (2444-28-2) + 2,6-Di-tert-butyl-1,4-benzoquinone (719-22-2)

Guidance literature:

With trifluoroacetic acid; at 20 ℃; for 0.25h;

DOI:10.1007/BF00948250

Reference yield: 30.0%

sulfure de di tert-butyle (107-47-1) → di-tert-butyl disulfide (110-06-5) + tert-butyl trifluoroacetate (400-52-2)

Guidance literature:

With bis-[(trifluoroacetoxy)iodo]benzene; In chloroform; at 20 ℃; for 24h;

upstream raw materials:

diethyl ether

trifluoroacetic anhydride

tert-butyl alcohol

2,4,6,2',4',6'-hexa-tert-butyl-4,4'-peroxy-bis-cyclohexa-2,5-dienone

Downstream raw materials:

trifluoromethan

trifluoroacetate

isobutene

acetic acid methyl ester

Refernces

• 1、 Bloodworth, A. J.,Chan, Kam Hung,Cooksey, Christopher J.,Hargreaves, Neville. "Oxymetallation. Part 23. Peroxymercuriation of Bicycloalkanes". . p. 1923 - 1930. Retrieved 2007/10/02.
• 2、 Barbas, Dimitris,Spyroudis, Spyros,Varvoglis, Anastasios. "Oxidation of Organic Sulfides with benzene". . p. 2201 - 2214. Retrieved 2007/10/02.