Nickel, [1,1,1-trimethyl-N-(trimethylsilyl)silanaminato]bis(triphenylphosphine)-

Base Information

Chemical Name:Nickel, [1,1,1-trimethyl-N-(trimethylsilyl)silanaminato]bis(triphenylphosphine)-
CAS No.:38685-20-0
Molecular Formula:C42H48NNiP2Si2
Molecular Weight:743.658
Hs Code.:

Synonyms:

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Chemical Property of Nickel, [1,1,1-trimethyl-N-(trimethylsilyl)silanaminato]bis(triphenylphosphine)-

Chemical Property:

Purity/Quality:

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MSDS Files:: SDS file from LookChem

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Technology Process of Nickel, [1,1,1-trimethyl-N-(trimethylsilyl)silanaminato]bis(triphenylphosphine)-

There total 2 articles about Nickel, [1,1,1-trimethyl-N-(trimethylsilyl)silanaminato]bis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 15169-64-9
chlorotris(triphenylphosphine)nickel

: 4039-32-1
lithium hexamethyldisilazane

: 38685-20-0
nickel(I) bis(triphenylphosphine)-bis(trimethylsilyl)amide

Guidance literature:: With triphenylphosphine; In toluene; at -40 - 20 ℃; for 4h; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.inorgchem.5b02497

Reference yield: 45.0%

: 14264-16-5,53996-95-5,62075-39-2,39716-73-9
bis(triphenylphosphine)nickel(II) chloride

: 4039-32-1
lithium hexamethyldisilazane

: 38685-20-0
nickel(I) bis(triphenylphosphine)-bis(trimethylsilyl)amide

Guidance literature:: In toluene; at 80 ℃; for 2h; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.inorgchem.5b02497

Reference yield: 82.0%

: 880169-37-9
1,1-bis(diphenylphosphino)-2-phenylhydrazine

: 38685-20-0
nickel(I) bis(triphenylphosphine)-bis(trimethylsilyl)amide

: Ni((C₆H₅)2PNP(C₆H₅)2N(C₆H₅))2

: Ni((C₆H₅)2PN(NHC₆H₅)P(C₆H₅)2)2

Guidance literature:: In toluene; byproducts: HN(Si(CH3)3)2, P(C6H5)3; in vac. or under Ar atm. using Schlenk techniques; mixt. of toluene soln. of diphosphinohydrazine and Ni complex was maintained at 20°C for 24 h; toluene removed (vac.); ether added; crystals formed overnight; filtered; washed (cold ether); dried (vac.); mother liquor heated at 40°Cfor 10 h; kept for 3 ds at 20°C; crystals were obtained; recryst d. (warm ether); elem. anal.;
DOI:10.1016/j.jorganchem.2005.10.030