Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine)

Base Information

• Chemical Name: Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine)
• CAS No.: 1119944-29-4
• Molecular Formula: C₄₂H₄₀NiPS
• Molecular Weight: 666.509
• Mol file: 1119944-29-4.mol

Synonyms:Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine)

Chemical Property of Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine)

There total 1 articles about Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

nickel(I) bis(triphenylphosphine)-bis(trimethylsilyl)amide (38685-20-0) + 2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol (157590-41-5) → Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine) (1119944-29-4)

Guidance literature:

In toluene; (N2), Schlenk techniques; at room temp. addn. of soln. of thiol in toluene to soln. of nickel compd. in toluene, stirring for 1 h; evapn. to dryness, washing with pentane, extn. with ether, concn., storage at -30°C, isolation of crystals, elem. anal.;

DOI:10.1021/ic802276w

Reference yield: 63.0%

tert-butylisonitrile (119072-55-8,7188-38-7) + Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine) (1119944-29-4) → Ni(CN-t-Bu)(μ-2,6-dimesitylphenylthiolate)]2 (1119944-33-0)

Guidance literature:

In toluene; (N2), Schlenk techniques; at -80°C, addn. of 0.5 M toluene soln. of (H3C)3CNC to soln. of nickel compd. in toluene, warming to room temp., stirring for 30 min at room temp.; evapn. to dryness, washing with hexane, elem. anal.;

DOI:10.1021/ic802276w

Reference yield: 44.0%

Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(triphenylphosphine) (1119944-29-4) + [1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene (141556-42-5) → Ni(2,6-((η2-mesityl)mesityl)phenylthiolate)(1,3-bis-(2,4,6-trimethylphenyl)imidazolin-2-ylidene)

Guidance literature:

In toluene; (N2), Schlenk techniques; at room temp. addn. of soln. of C3H2N2(C6H2(CH3)3)2 in toluene to soln. of nickel compd. in toluene, stirring for 3 h; centrifugation, evapn. of supernatant to dryness, washing with pentane, elem. anal.;

DOI:10.1021/ic802276w

upstream raw materials:

nickel(I) bis(triphenylphosphine)-bis(trimethylsilyl)amide

2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol

Downstream raw materials:

Ni(CN-t-Bu)(μ-2,6-dimesitylphenylthiolate)]2

[Ni(CO)(2,6-dimesitylphenylthiolate)2(triphenylphosphine)]

bis(triphenylphosphine)nickel⁽⁰⁾ dicarbonyl

Ni(N,N'-diethyl-3,7-diazanonane-1,9-dithiolato)Ni(Me)(S-2,6-dimesitylphenyl)