Trifluoroacetic acid 1-methylethenyl ester

Base Information

• Chemical Name: Trifluoroacetic acid 1-methylethenyl ester
• CAS No.: 400-39-5
• Molecular Formula: C5H5F3O2
• Molecular Weight: 154.089
• Mol file: 400-39-5.mol

Synonyms:i-propenyl trifluoroacetate;Acetic acid,trifluoro-,isopropenyl ester;Acetic acid,trifluoro-,1-methylethenyl ester;Isopropenyl-trifluoracetat;Acetic acid, trifluoro-, 1-methylethenyl ester;trifluoro-acetic acid isopropenyl ester;Trifluor-essigsaeure-isopropenylester;trifluoro-acetic acid,1-methylethenyl ester;

Chemical Property of Trifluoroacetic acid 1-methylethenyl ester

Chemical Property:

• Boiling Point: 53.4±40.0 °C(Predicted)
• PSA: 26.30000
• Density: 1.224±0.06 g/cm3(Predicted)
• LogP: 1.62550

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Trifluoroacetic acid 1-methylethenyl ester

There total 3 articles about Trifluoroacetic acid 1-methylethenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trifluoracetyl chloride (354-32-5) + acetone enolate ion (24262-31-5) → 1,1,1-Trifluoro-2,4-pentanedione (367-57-7) + i-propenyl trifluoroacetate (400-39-5)

Guidance literature:

Mechanism; other ambient nucleophiles;

DOI:10.1021/ja00072a044

Reference yield:

trifluoroacetic acid (76-05-1) + prop-1-yne (74-99-7) → i-propenyl trifluoroacetate (400-39-5)

Guidance literature:

With zinc diacetate; at 200 ℃;

Reference yield:

trifluoroacetyl bromide (354-31-4) + (acetylmethyl)mercury chloride (6704-27-4) → i-propenyl trifluoroacetate (400-39-5)

Guidance literature:

In nitrobenzene;

upstream raw materials:

trifluoroacetic acid

prop-1-yne

trifluoroacetyl bromide

(acetylmethyl)mercury chloride

Downstream raw materials:

trifluoroacetic acid-methyl ester

(t-C₄H₉)2SbCH₂COCH₃

ethyl trifluoroacetate,

(Di-t-butylstibyl)aceton

Refernces