acetone enolate ion

Base Information

• Chemical Name: acetone enolate ion
• CAS No.: 24262-31-5
• Molecular Formula: C₃H₅O
• Molecular Weight: 57.0721
• Mol file: 24262-31-5.mol

Synonyms:acetone enolate ion

Chemical Property of acetone enolate ion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of acetone enolate ion

There total 9 articles about acetone enolate ion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 3.0%

phenylnitrene anion radical (74586-02-0) + acetone (67-64-1) → methyl radical (2229-07-4) + acetone enolate ion (24262-31-5) + anilino radical (2348-49-4) + N-phenylacetamide anion (61057-08-7) + C9H11NO(1-)

Guidance literature:

Product distribution; Mechanism; Rate constant; flowing afterglow apparatus; quadrupole MS-monitoring of the relative concentrations of PhN(-*) and products; relative rate constants for the addition reactions and total absolute constant; a series of carbonyl compounds investigated;

DOI:10.1021/ja00393a032

Reference yield:

2,3,3-Trimethyl-butan-2-ol anion (113534-05-7) → Isobutane (75-28-5,40921-86-6) + acetone enolate ion (24262-31-5)

Guidance literature:

Irradiation;

DOI:10.1021/ja00217a003

Reference yield:

acetone (67-64-1) → 4-methyl-pent-3-en-2-one (141-79-7) + acetone enolate ion (24262-31-5)

Guidance literature:

With iron(III) oxide; for 4h; Mechanism; chemisorb adsorbtion of acetone on α-Fe2O3 surface via study of IR spectrum;

DOI:10.1039/f19827802911

upstream raw materials:

2-methyl(1,1,1-²H₃)propan-2-ol

2,3,3-Trimethyl-butan-2-ol anion

2-Phenyl-propan-2-ol anion

propionaldehyde

Downstream raw materials:

1,1,1-trifluoroacetone enolate anion

acetone

2-Methoxypropene

butanone

Refernces

• 1、 Tumas, William,Foster, Robert F.,Pellerite, Mark J.,Brauman, John I.. "A Stepwise Mechanism for Gas-Phase Unimolecular Ion Decompositions. Isotope Effects in the Fragmentation of tert-Butoxide Anion". . p. 961 - 970. Retrieved 2007/10/02.
• 2、 McDonald, Richard N.,Chowdhury, A. Kesem. "Gas-Phase Nucleophilic Reactivities of Phenylnitrene (PhN-*) and Sulfur Anion Radicals (S-/.) at sp3 and Carbonyl Carbon". . p. 198 - 207. Retrieved 2007/10/02.