1,3,5-Benzenetripropanoic acid, trimethyl ester

Base Information

• Chemical Name: 1,3,5-Benzenetripropanoic acid, trimethyl ester
• CAS No.: 41009-90-9
• Molecular Formula: C18H24O6
• Molecular Weight: 336.385
• Mol file: 41009-90-9.mol

Synonyms:

Chemical Property of 1,3,5-Benzenetripropanoic acid, trimethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3,5-Benzenetripropanoic acid, trimethyl ester

There total 9 articles about 1,3,5-Benzenetripropanoic acid, trimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

(E)-3-[3,5-Bis-((E)-2-methoxycarbonyl-vinyl)-phenyl]-acrylic acid methyl ester → 1,3,5-tris(2-carbomethoxyethyl)benzene (41009-90-9)

Guidance literature:

With hydrogen; palladium on activated charcoal; In tetrahydrofuran; at 40 - 50 ℃; for 1h; under 2585.7 Torr;

DOI:10.1080/00304949709355214

Reference yield: 78.0%

methanol (67-56-1) + TAB002 (18226-49-8) → 1,3,5-tris(2-carbomethoxyethyl)benzene (41009-90-9)

Guidance literature:

With sulfuric acid; for 23h; Heating;

DOI:10.1246/bcsj.69.3317

Reference yield:

1,3,5-trisbromobenzene (626-39-1) → 1,3,5-tris(2-carbomethoxyethyl)benzene (41009-90-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 63 percent / Pd(OAc)2, tri-(o-tolyl)phosphine, Et₃N / acetonitrile / 5 h / Heating

2: 85 percent / H₂ / 5percent Pd/C / tetrahydrofuran / 1 h / 40 - 50 °C / 2585.7 Torr

With palladium diacetate; hydrogen; triethylamine; tris-(o-tolyl)phosphine; palladium on activated charcoal; In tetrahydrofuran; acetonitrile;

DOI:10.1080/00304949709355214

upstream raw materials:

methanol

TAB₀₀₂

1,3,5-trisbromobenzene

1,3,5-Tris(bromomethyl)benzene

Downstream raw materials:

1,3,5-tris[3-(imidazol-1-yl)propyl]benzene

1,3,5-tris(3'-bromopropyl)benzene

TAB₀₀₂

1,3,5-tris(3-hydroxypropyl)benzene