Iron, tetracarbonyl(triphenylphosphine)-

Base Information

• Chemical Name: Iron, tetracarbonyl(triphenylphosphine)-
• CAS No.: 14649-69-5
• Molecular Formula: C₂₂H₁₅FeO₄P
• Molecular Weight: 430.179
• NSC Number: 175503
• Mol file: 14649-69-5.mol

Synonyms:Iron, tetracarbonyl(triphenylphosphine)-;14649-69-5;GHXDZMLBRWBQAM-UHFFFAOYSA-N;NSC175503;NSC-175503

Chemical Property of Iron, tetracarbonyl(triphenylphosphine)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 431.013557
• Heavy Atom Count: 28
• Complexity: 370

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.[Fe]

Technology Process of Iron, tetracarbonyl(triphenylphosphine)-

There total 105 articles about Iron, tetracarbonyl(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

dicarbonyl{O-4-η-((E)-4-phenylbut-3-en-2-one)}(triphenylphosphine)iron → iron pentacarbonyl (13463-40-6,37220-42-1) + tetracarbonyl(triphenylphosphine)iron (35679-07-3,14649-69-5) + tricarbonyl(benzylideneacetone)iron

Guidance literature:

With carbon monoxide; In Petroleum ether; thermal decompn. in petroleum ether at 70°C under 1 atm of CO; analyzed by IR;

DOI:10.1016/0022-328X(84)80113-8

Reference yield: 75.0%

1,1-Diphenylethylene (530-48-3) + HFe(CO)2NO(P(C6H5)3) → bis(triphenylphosphine)dinitrosyliron + tricarbonyl bis(triphenylphosphine) iron (14741-34-5,21255-52-7) + tetracarbonyl(triphenylphosphine)iron (35679-07-3,14649-69-5) + Fe(CO)(NO)2(P(C6H5)3) + 1,1'-ethylidenebis-benzene (612-00-0)

Guidance literature:

In diethyl ether; to soln. FeH(CO)2(NO)(P(C6H5)3) in ether stoich. amt. 1,1-diphenyl ethylene added and soln. stirred for 15 min;

Reference yield: 54.0%

bis(μ,η2-decanoyl)hexacarbonyldiiron → tetracarbonyl(triphenylphosphine)iron (35679-07-3,14649-69-5) + 10-Nonadecanon (504-57-4)

Guidance literature:

With triphenylphosphine; In cyclohexane; byproducts: Fe(CO)3(P(C6H5)3)2, Fe3(CO)12; (N2); added a soln. of triphenyl phosphine, n-tridecane and cyclohexane to Fe-complex; stirred for 2 h at room temp.; cooled to -78°C; IR, GLPC, HPLC; Kinetics;

upstream raw materials:

triphenylphosphine

triiron dodecarbonyl

iron

iron pentacarbonyl

Downstream raw materials:

tetracarbonyl nickel

{Et₄N}{HFe(CO)3PPh₃}

dicarbonyl{2,3-η:5,6-η-(1,3-cyclooctadiene)}(triphenylphosphine)iron

triphenylphosphine-tricarbonyl-iodo-iron-tin(IV)-triiodide