2-(1-Cyclohexenyl)naphthalene

Base Information

• Chemical Name: 2-(1-Cyclohexenyl)naphthalene
• CAS No.: 54607-03-3
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• Hs Code.: 2902909090
• Mol file: 54607-03-3.mol

Synonyms:2-cyclohex-1-en-1-ylnaphthalene;1-(2-naphthyl)cyclohex-1-ene;1-(2-naphthyl)-1-cyclohexene;Naphthalene,2-(1-cyclohexen-1-yl);naphthalenecyclohexene;2-(1-cyclohexenyl)naphthalene;2-(1-Cyclohexen-1-yl)naphthalene;1-(2-naphthyl)cyclohexene;

Chemical Property of 2-(1-Cyclohexenyl)naphthalene

Chemical Property:

• PSA: 0.00000
• LogP: 4.79720

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(1-Cyclohexenyl)naphthalene

There total 22 articles about 2-(1-Cyclohexenyl)naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

ethyl-(6-cyclohex-1-enyl-[2]naphthyl)-ether → 2-(cyclohex-1-en-1-yl)naphthalene (54607-03-3)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; 1,3-bis(adamantan-2-yl)imidazolin-2-yliden chloride; sodium t-butanolate; In toluene; at 160 ℃; for 18h;

DOI:10.1039/c5sc00305a

Reference yield: 90.0%

2-naphthyl pivalate (1503-86-2) + cyclohexene (110-83-8) → 2-(cyclohex-1-en-1-yl)naphthalene (54607-03-3)

Guidance literature:

With nickel(II) bromide dimethoxyethane; zinc; (R,R)-1,2-bis(2,5-diphenylphospholanyl)ethane; In toluene; at 100 ℃; for 24h; Inert atmosphere; Glovebox; Schlenk technique; Molecular sieve;

DOI:10.1039/d1cc00634g

Reference yield: 89.0%

1-(naphthalen-2-yl)cyclohexan-1-ol → 2-(cyclohex-1-en-1-yl)naphthalene (54607-03-3)

Guidance literature:

With acetic acid; at 118 ℃; for 1h;

DOI:10.1021/ja4100595

upstream raw materials:

2-naphthalenylmagnesium bromide

cyclohexanone

naphthalene-2-boronic acid

phosphoric acid cyclohex-1-enyl ester diphenyl ester

Downstream raw materials:

(+/-)-(2t-[2]naphthyl-3-oxo-cyclohex-r-yl)-acetic acid

2-methoxy-2-(2-naphthyl)cyclohexanone

2-naphthyl-1-(tert-butyldimethylsilyloxy)cyclohex-1-ene

2-naphthyl-1-(trimethylsilyloxy)cyclohex-1-ene

Refernces

• 1、 Cao, Zhi-Chao,Xie, Si-Jun,Fang, Huayi,Shi, Zhang-Jie. "Ni-Catalyzed Cross-Coupling of Dimethyl Aryl Amines with Arylboronic Esters under Reductive Conditions". supporting information. p. 13575 - 13579. Retrieved 2018/10/24.
• 2、 Tobisu, Mamoru,Morioka, Toshifumi,Ohtsuki, Akimichi,Chatani, Naoto. "Nickel-catalyzed reductive cleavage of aryl alkyl ethers to arenes in absence of external reductant". . p. 3410 - 3414. Retrieved 2015/05/27.