9-Octadecenoic acid, 13-hydroxy-12-oxo-, (Z)-

Base Information

• Chemical Name: 9-Octadecenoic acid, 13-hydroxy-12-oxo-, (Z)-
• CAS No.: 5502-89-6
• Molecular Formula: C18H32O4
• Molecular Weight: 312.45
• Mol file: 5502-89-6.mol

Synonyms:13-Hydroxy-12-oxo-cis-9-octadecensaeure;13-hydroxy-12-oxo-octadeca-cis-9-enoic acid;12-Oxo-13-hydroxy-cis-9-octadecensaeure;13-hydroxy-12-oxo-octadec-cis-9-enoic acid;9-Octadecenoic acid,13-hydroxy-12-oxo-,(Z);

Chemical Property of 9-Octadecenoic acid, 13-hydroxy-12-oxo-, (Z)-

Chemical Property:

• PSA: 74.60000
• LogP: 4.25830

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-Octadecenoic acid, 13-hydroxy-12-oxo-, (Z)-

There total 3 articles about 9-Octadecenoic acid, 13-hydroxy-12-oxo-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

linoleic acid (60-33-3,116745-32-5,26085-09-6,64080-88-2,7049-66-3,949900-18-9,60476-23-5,6144-28-1,67922-65-0,89718-18-3) → azelaic acid (123-99-9,26776-28-3) + (3Z)-dodecene-1,12-dioic acid (189034-80-8) + 9-hydroxynonanoic acid (3788-56-5) + (12Z)-9-hydroxy-10-oxo-12-octadecenoic acid (5503-03-7,70144-92-2,26369-27-7) + 13-hydroxy-12-oxo-octadeca-cis-9-enoic acid (5502-89-6) + (9Z)-11-hydroxy-12,13-epoxy-9-octadecenoic acid + (4Z)-2-pentyl-4-tridecene-1,13-dioic acid + (2’Z)-2-(2’-octenyl)-decane-1,10-dioic acid + (2’Z,5’Z)-2-(2’,5’-octadienyl)-decane-1,10-dioic acid + (12Z)-10-oxo-11-hydroxy-12-octadecenoic acid + (13S,9Z,11E)-13-hydroxy-9,11-octadecadienoic acid (29623-28-7) + (9S,10E,12Z)-9-hydroxy-10,12-octadecadienoic acid (73543-67-6)

Guidance literature:

With oxygen; for 0.5h; Enzymatic reaction;

DOI:10.1002/open.201800045

Reference yield:

linoleic acid (60-33-3,116745-32-5,26085-09-6,64080-88-2,7049-66-3,949900-18-9,60476-23-5,6144-28-1,67922-65-0,89718-18-3) → 13-hydroxy-12-oxo-octadeca-cis-9-enoic acid (5502-89-6) + (8E,1'E,3'Z)-9-(1',3'-nonadienyloxy)-8-nonenoic acid (52761-34-9) + 12-[1′(E)-hexenyloxy]-9(Z),11(E)-dodecadienoic acid (169217-38-3) + (±)-cis-12-oxo-10-phytoenoic acid

Guidance literature:

With oxygen; for 0.5h; pH=7.5; aq. buffer;

DOI:10.1016/j.phytochem.2008.09.011

Reference yield:

linoleic acid (60-33-3,116745-32-5,26085-09-6,64080-88-2,7049-66-3,949900-18-9,60476-23-5,6144-28-1,67922-65-0,89718-18-3) → 13-hydroxy-12-oxo-octadeca-cis-9-enoic acid (5502-89-6) + (9E,12E)-9-Hydroperoxy-octadeca-9,12-dienoic acid + linoleic acid 13-hydroperoxide + (9E,12Z)-13-Hydroperoxy-octadeca-9,12-dienoic acid

Guidance literature:

With eggplant lipoxygenase enzyme; In water; Product distribution; 0.1M Na-Pi buffer (pH 6.5);

DOI:10.1016/0031-9422(80)80169-5

upstream raw materials:

linoleic acid