Phenyl dimethylphosphinate

Base Information

• Chemical Name: Phenyl dimethylphosphinate
• CAS No.: 57244-61-8
• Molecular Formula: C8H11O2P
• Molecular Weight: 170.148
• DSSTox Substance ID: DTXSID80604166
• Nikkaji Number: J753.047A
• Wikidata: Q82501949
• Mol file: 57244-61-8.mol

Synonyms:phenyl dimethylphosphinate;57244-61-8;SCHEMBL676524;DTXSID80604166

Chemical Property of Phenyl dimethylphosphinate

Chemical Property:

• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 170.04966659
• Heavy Atom Count: 11
• Complexity: 156

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CP(=O)(C)OC1=CC=CC=C1

Technology Process of Phenyl dimethylphosphinate

There total 1 articles about Phenyl dimethylphosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.8%

dimethylphosphinic acid chloride (1111-92-8) + phenol (108-95-2,27073-41-2) → phenyl dimethylphosphinate (57244-61-8)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 30 ℃; Inert atmosphere;

Reference yield:

phenyl dimethylphosphinate (57244-61-8) + 4-tert-butylphenyl 2,3-epoxypropyl ether (3101-60-8) → C21H29O4P

Guidance literature:

With dmap; at 160 ℃; for 2h; Inert atmosphere;

Reference yield:

ethanol (64-17-5) + phenyl dimethylphosphinate (57244-61-8) → O-ethyl(dimethyl) phosphinate (2511-19-5) + phenol (108-95-2,27073-41-2)

Guidance literature:

With potassium hydroxide; 18-crown-6 ether; at 25 ℃; Kinetics;

DOI:10.1039/b314886f

upstream raw materials:

dimethylphosphinic acid chloride

phenol

Downstream raw materials:

O-ethyl(dimethyl) phosphinate

phenol

C₈H₁₂NOP

Refernces

• 1、 -. "Phosphorus-containing compound, and curable epoxy resin composition containing same". Paragraph 0067; 0068; 0069. . Retrieved 2016/10/27.
• 2、 Buncel, Erwin,Albright, Kendall G.,Onyido, Ikenna. "Nucleophilic displacement on 4-nitrophenyl dimethyl phosphinate by ethoxide ion: Alkali metal ion catalysis and mechanism". . p. 601 - 610. Retrieved 2007/10/03.