Chloridovanadic acid diethyl ester

Base Information

• Chemical Name: Chloridovanadic acid diethyl ester
• CAS No.: 1635-99-0
• Molecular Formula: C4H10 Cl O3 V
• Molecular Weight: 192.516
• Mol file: 1635-99-0.mol

Synonyms:Ethylchlorovanadate(V) (6CI); Vanadium, chlorodiethoxyoxo- (7CI,8CI);Bis(ethoxy)vanadium oxychloride; Chlorobis(ethoxo)oxovanadium;Chlorobis(ethoxy)oxovanadium; Chlorodiethoxyoxovanadium; NSC 79525; Vanadyldiethoxy chloride; Vanadyl diethoxy monochloride; Vanadyl monochloro diethylate

Chemical Property of Chloridovanadic acid diethyl ester

Chemical Property:

• Vapor Pressure: 82.8mmHg at 25°C
• Boiling Point: 72.6°Cat760mmHg
• Flash Point: 8.9°C
• PSA: 35.53000
• Density: g/cm³
• LogP: 1.54510

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Chloridovanadic acid diethyl ester

There total 1 articles about Chloridovanadic acid diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

vanadium(V) oxytriethoxide (1686-22-2) + vanadium(V) oxychloride (7727-18-6) → oxovanadium(V) ethoxydichloride (1801-77-0) + chloroorthovanadic acid diethyl ester (1635-99-0)

Guidance literature:

In tetrachloromethane;

Reference yield: 81.0%

2,6-diisopropylphenyl isocyanate (28178-42-9) + chloroorthovanadic acid diethyl ester (1635-99-0) → [(V(NC6H3(iPr)2)Cl(OEt)2)2] (1253938-91-8)

Guidance literature:

In neat (no solvent); byproducts: CO2; (N2); stirring mixt. of vanadium compd. and isocyanate deriv. at 115°C for 3 h; cooling to room temp., addn. of pentane, filtration, cooling to 5°C, isolation of solid, elem. anal.;

DOI:10.1039/c0dt00064g

Reference yield:

chloroorthovanadic acid diethyl ester (1635-99-0) → oxovanadium(V) trimethoxide (7681-91-6)

Guidance literature:

With methanol; In methanol; byproducts: C2H5OH, HCl; boiling a soln. of VO(OC2H5)2Cl in methanol under complete exclusion ofmoisture under Ar;

upstream raw materials:

vanadium(V) oxytriethoxide

vanadium(V) oxychloride

Downstream raw materials:

oxovanadium(V) trimethoxide

[(V(NC₆H₃(iPr)2)Cl(OEt)2)2]