DICHLOROETHOXYOXOVANADIUM (V)

Base Information

• Chemical Name: DICHLOROETHOXYOXOVANADIUM (V)
• CAS No.: 1801-77-0
• Molecular Formula: C2H5 Cl2 O2 V
• Molecular Weight: 182.908
• Hs Code.: 2914700090
• Mol file: 1801-77-0.mol

Synonyms:Ethyldichlorovanadate(V) (6CI); Vanadium, dichloroethoxyoxo- (7CI,8CI);Dichloro(ethoxy)oxovanadium; Dichloroethanolatooxovanadium;Dichloroethoxyvanadium oxide; Ethoxyvanadyl dichloride; Oxovanadium dichlorideethoxide; Vanadyl ethoxydichloride

Chemical Property of DICHLOROETHOXYOXOVANADIUM (V)

Chemical Property:

• PSA: 29.46000
• LogP: 0.71810

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DICHLOROETHOXYOXOVANADIUM (V)

There total 4 articles about DICHLOROETHOXYOXOVANADIUM (V) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

ethyl trimethylsilyl ether (1825-62-3) + vanadium(V) oxychloride (7727-18-6) → oxovanadium(V) ethoxydichloride (1801-77-0)

Guidance literature:

In dichloromethane; byproducts: (CH3)3SiCl; (N2); addn. of 2 equiv. of silane deriv. to CH2Cl2 soln. of vanadium compd. at room temp., stirring for 2 h at room temp.; evapn., elem. anal.;

DOI:10.1039/c0dt00064g

Reference yield:

ethanol (64-17-5) + vanadium(V) oxychloride (7727-18-6) → oxovanadium(V) ethoxydichloride (1801-77-0)

Guidance literature:

In chloroform-d1; in the presence of MS4A molecular sieve, there is no reaction in the presence of collidine;

DOI:10.1246/cl.2001.1324

Reference yield:

sodium ethanolate (141-52-6) → oxovanadium(V) ethoxydichloride (1801-77-0)

Guidance literature:

With vanadium oxychloride; benzene;

upstream raw materials:

sodium ethanolate

vanadium(V) oxytriethoxide

vanadium(V) oxychloride

ethanol

Downstream raw materials:

ethyl 4,5-dihydro-2,5-dimethyl-5-phenylfuran-3-carboxylate

Phenetole

3-ethoxycyclohexan-1-one

ethyl 2-hydroxy-6-methylbenzoate

Refernces

• 1、 Romero-Fernandez, Javier,Carrillo-Hermosilla, Fernando,Antinolo, Antonio,Alonso-Moreno, Carlos,Rodriguez, Ana M.,Lopez-Solera, Isabel,Otero, Antonio. "Oxo- and imido-alkoxide vanadium complexes as precatalysts for the guanylation of aromatic amines". . p. 6419 - 6425. Retrieved 2010/09/06.
• 2、 Hirao, Toshikazu,Mori, Makoto,Ohshiro, Yoshiki. "Oxovanadium(V)-Induced Ring-Opening Oxygenation of Cyclic Ketones in Alcohol". . p. 2399 - 2400. Retrieved 2007/10/02.