1801-77-0 Usage
General Description
Dichloroethoxyoxovanadium (V), also known as vanadium(V) oxydichloroethoxide, is a chemical compound with the formula V(OEt)Cl2. It is a coordination complex of vanadium(V) with two ethoxy (OEt) groups and two chloride (Cl) ions. DICHLOROETHOXYOXOVANADIUM (V) is commonly used as a catalyst in organic synthesis, particularly in the production of specialty chemicals and pharmaceuticals. It can also be used as a reagent in various chemical reactions and as a research tool in the study of vanadium chemistry. Dichloroethoxyoxovanadium (V) has also shown potential biological activity and is being investigated for its potential applications in medicine, particularly in the treatment of diabetes and cancer.
Check Digit Verification of cas no
The CAS Registry Mumber 1801-77-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,8,0 and 1 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1801-77:
(6*1)+(5*8)+(4*0)+(3*1)+(2*7)+(1*7)=70
70 % 10 = 0
So 1801-77-0 is a valid CAS Registry Number.
1801-77-0Relevant articles and documents
Enantioselective radical cross-coupling reactions of silyl enol ethers using chiral oxovanadium
Kurihara, Masaaki,Hayashi, Taeko,Miyata, Naoki
, p. 1324 - 1325 (2001)
Asymmetric induction was observed in radical cross-coupling reactions of silyl enol ethers using chiral oxovanadium generated in situ from 8-phenylmenthol and vanadium oxytrichloride in the presence of MS4A (molecular sieves-4A).
High valence vanadium complex promoted selective rearrangement of epoxides to aldehydes or ketones
Martinez, Fernando,Campo, Carmen del,Llama, Emilio F.
, p. 1749 - 1752 (2008/10/08)
High valence vanadium complexes induce the selective ring opening of epoxides. The monosubstituted epoxides are isomerized with complete regioselectivity each forming a single carbonyl compound exclusively. Likewise a highly regioselective isomerization of 1,1-disubstituted or 1,1,2-trisubstituted epoxides was observed in all reactions.
