TRI-I-PROPYLTIN CHLORIDE

Base Information

• Chemical Name: TRI-I-PROPYLTIN CHLORIDE
• CAS No.: 14101-95-2
• Molecular Formula: C9H21 Cl Sn
• Molecular Weight: 283.429
• Hs Code.: 2931900090
• Mol file: 14101-95-2.mol

Synonyms:Stannane,chlorotriisopropyl- (8CI); Triisopropyltin chloride (6CI);Chlorotriisopropylstannane; Triisopropylchlorostannane

Chemical Property of TRI-I-PROPYLTIN CHLORIDE

Chemical Property:

• Vapor Pressure: 0.173mmHg at 25°C
• Boiling Point: 219.8°Cat760mmHg
• Flash Point: 86.7°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 4.40070

Purity/Quality:

98%Min ^*data from raw suppliers

Tri-i-propyltin chloride, min. 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): A poison by ingestion.
• Hazard Codes: A poison by ingestion.

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRI-I-PROPYLTIN CHLORIDE

There total 14 articles about TRI-I-PROPYLTIN CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

bromo-triphenyl-methane (596-43-0) + tetraisopropyltin (2949-42-0) → propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + triphenylmethane (519-73-3) + chlorotriisopropylstannane (14101-95-2)

Guidance literature:

In further solvent(s); 22 h, in C2H4Cl2, boiling;

Reference yield:

tetraisopropyltin (2949-42-0) → chloroform (67-66-3,8013-54-5) + 1,1,1,3-tetrachlorobutane (13275-19-9) + chlorotriisopropylstannane (14101-95-2)

Guidance literature:

With tetrachloromethane; heating to 60°C during 32 h;

Reference yield:

dimethyltin dichloride (753-73-1) + (iso-C3H7)3SnCH3 (19411-59-7) → trimethyltin(IV)chloride (1066-45-1) + chlorotriisopropylstannane (14101-95-2)

Guidance literature:

at varying temp.;; Kinetics;

upstream raw materials:

O,O-dimethylphosphorylsulfenyl chloride

tetraisopropyltin

titanium tetrachloride

bromo-triphenyl-methane

Downstream raw materials:

triisopropyltin hydride

Refernces

• 1、 Kutyrev, G. A.,Vinokurov, A. I.,Cherkasov, R. A.,Pudovik, A. N.. "REACTIVITY OF PHOSPHONOSULFENYL CHLORIDES. REACTIONS WITH TETRAALKYLSTANNANES". . p. 289 - 291. Retrieved 2007/10/02.