Methyl 2-(1-phenylethylidene)hydrazinecarbodithioate

Base Information

• Chemical Name: Methyl 2-(1-phenylethylidene)hydrazinecarbodithioate
• CAS No.: 26155-38-4
• Molecular Formula: C10H12 N2 S2
• Molecular Weight: 224.351
• Hs Code.: 2930909090
• DSSTox Substance ID: DTXSID50949031
• Mol file: 26155-38-4.mol

Synonyms:177540-74-8;methyl 2-(1-phenylethylidene)hydrazinecarbodithioate;DTXSID50949031;HMS2604O09;AKOS030697056;Methyl hydrogen (1-phenylethylidene)carbonodithiohydrazonate

Chemical Property of Methyl 2-(1-phenylethylidene)hydrazinecarbodithioate

Chemical Property:

• Vapor Pressure: 0.000139mmHg at 25°C
• Boiling Point: 333.1°Cat760mmHg
• Flash Point: 155.3°C
• PSA: 81.78000
• Density: 1.14g/cm³
• LogP: 3.03900
• XLogP3: 2.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 224.04419074
• Heavy Atom Count: 14
• Complexity: 220

Purity/Quality:

97% ^*data from raw suppliers

METHYL 2-(1-PHENYLETHYLIDENE)HYDRAZINECARBODITHIOATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=NNC(=S)SC)C1=CC=CC=C1

Technology Process of Methyl 2-(1-phenylethylidene)hydrazinecarbodithioate

There total 3 articles about Methyl 2-(1-phenylethylidene)hydrazinecarbodithioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

hydrazinecarbodithioic acid methyl ester (5397-03-5) + acetophenone (98-86-2) → (1-phenyl-ethylidene)-hydrazinecarbodithioic acid methyl ester (26155-38-4)

Guidance literature:

With hydrogenchloride; In ethanol; for 24h; Heating;

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + acetophenone (98-86-2) + methyl iodide (74-88-4) → (1-phenyl-ethylidene)-hydrazinecarbodithioic acid methyl ester (26155-38-4)

Guidance literature:

With potassium hydroxide; hydrazine; Multistep reaction; 1.) ethanol, 0 deg C, 1 h, 2.) ethanol, from 0 deg C to RT, 3 h;

DOI:10.1246/bcsj.69.1043

Reference yield:

→ (1-phenyl-ethylidene)-hydrazinecarbodithioic acid methyl ester (26155-38-4)

Guidance literature:

upstream raw materials:

hydrazinecarbodithioic acid methyl ester

acetophenone

carbon disulfide

methyl iodide

Downstream raw materials:

N⁴-(2-aminophenyl)-2-(1-phenylethylidene)hydrazinecarbothioamide

N-(1,3-Dimethyl-imidazolidin-2-ylidene)-N'-[1-phenyl-eth-(E)-ylidene]-hydrazine

C₂₆H₂₁N₅O₃S

C₂₀H₂₂N₄S₄