N-methylolmethacrylamide

Base Information

• Chemical Name: N-methylolmethacrylamide
• CAS No.: 923-02-4
• Deprecated CAS: 134617-55-3
• Molecular Formula: C5H9NO2
• Molecular Weight: 115.132
• Hs Code.: 2924199090
• European Community (EC) Number: 213-086-1
• NSC Number: 2691
• UNII: 8BO2025ITR
• DSSTox Substance ID: DTXSID2027335
• Nikkaji Number: J39.892F
• Wikidata: Q27270148
• Mol file: 923-02-4.mol

Synonyms:MEAA cpd;N-methylolmethacrylamide

Chemical Property of N-methylolmethacrylamide

Chemical Property:

• Vapor Pressure: 7.28E-05mmHg at 25°C
• Melting Point: 53-55 oC
• Refractive Index: n20/D 1.43
• Boiling Point: 306.3 °C at 760 mmHg
• PKA: 13.08±0.10(Predicted)
• Flash Point: 139 °C
• PSA: 49.33000
• Density: 1.052 g/cm³
• LogP: 0.01940
• Water Solubility.: 600g/L at 20℃
• XLogP3: -0.1
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 115.063328530
• Heavy Atom Count: 8
• Complexity: 109

Purity/Quality:

98% ^*data from raw suppliers

N-(Hydroxymethyl)-2-methylacrylamide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22-40-43-68
• Safety Statements: 26-36/37/39-36/37-23

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)NCO
• Uses: N-(Hydroxymethyl)-2-methylacrylamide can be used for conditioning of fabrics.

Technology Process of N-methylolmethacrylamide

There total 2 articles about N-methylolmethacrylamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + Methacrylamide (79-39-0) → N-hydroxymethyl methacrylamide (923-02-4,26587-87-1)

Guidance literature:

With tetrachloromethane; sodium; xylene;

DOI:10.1021/ja01116a041

Reference yield:

→ N-hydroxymethyl methacrylamide (923-02-4,26587-87-1)

Guidance literature:

DOI:10.1002/apmc.1974.050390108

Reference yield:

methanol (67-56-1) + N-hydroxymethyl methacrylamide (923-02-4,26587-87-1) → N-(methoxymethyl)methacrylamide (3644-12-0)

Guidance literature:

With hydrogenchloride;

upstream raw materials:

formaldehyd

Methacrylamide

Downstream raw materials:

N-(methoxymethyl)methacrylamide

N,N'-methylenebisacrylamide

N-(methacryloylamino-methyl)-salicylamide