Technology Process of Iridium, carbonylchlorobis(dimethylphenylphosphine)dihydro-
There total 3 articles about Iridium, carbonylchlorobis(dimethylphenylphosphine)dihydro- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
benzene-d6;
soln. of Ir complex in C6D6 in NMR tube was satd. with H2 (1 atm. at 24-130°C); placed in const. temp. bath (+/-1°C); not isolated; monitored by (1)H NMR spectroscopy;
DOI:10.1021/ja0362611
- Guidance literature:
-
With
formic acid;
In
nitromethane-d3;
byproducts: CO2; Ar-atmosphere; addn. of two-fold excess of HCOOH to Ir-complex, 15 min at 28°C (observation of intermediates), standing for 48 h at 20°C; not isolated, detd. by (1)H-NMR spectroscopy; further intermediates: IrH(CO)(O2CH)2(PMe2Ph)2, IrH2Cl(CO)(PMe2Ph)2;
DOI:10.1039/DT9780001213
- Guidance literature:
-
In
benzene-d6;
Ar-atmosphere; addn. of H(13)COOH to Ir-complex, 15 min at 28°C (observation of intermediates), standing for 48 h at 20°C; not isolated, detd. by (1)H-NMR spectroscopy; further intermediate: IrH(CO)(O2(13)CH)2(PMe2Ph)2;
DOI:10.1039/DT9780001213
