Hexacarbonylvanadium

Base Information

• Chemical Name: Hexacarbonylvanadium
• CAS No.: 20644-87-5
• Molecular Formula: C₆H₆O₆V
• Molecular Weight: 219.004
• European Community (EC) Number: 237-849-3
• UNII: WA8Q7FLK2X
• Wikipedia: Vanadium_hexacarbonyl
• Wikidata: Q419078
• Mol file: 20644-87-5.mol

Synonyms:Hexacarbonylvanadium;carbon monoxide;vanadium;Vanadium hexacarbonyl;14024-00-1;WA8Q7FLK2X;VANADIUM CARBONYL [MI];VANADATE(1-), HEXACARBONYL-;(OC-6-11)-HEXACARBONYLVANADATE(1-);Q419078

Chemical Property of Hexacarbonylvanadium

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 218.913445
• Heavy Atom Count: 13
• Complexity: 10

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[V]

Technology Process of Hexacarbonylvanadium

There total 20 articles about Hexacarbonylvanadium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.0%

vanadium(III) chloride (7718-98-1) → (hexacarbonyl)vanadinate(1-) (20644-87-5)

Guidance literature:

With carbon monoxide; sodium; In tetrahydrofuran; Sonication; excess of Na sand added to VCl3 soln., flushed with CO (4.4 atm), maintained under CO during sonication at 10°C for 1000 min; not isolated, detected by IR;

DOI:10.1021/ja00334a073

Reference yield:

vanadium trichloride tristetrahydrofuran (19559-06-9) → (hexacarbonyl)vanadinate(1-) (20644-87-5)

Guidance literature:

With carbon monoxide; sodium; In tetrahydrofuran; Sonication; excess of Na sand added to VCl3(C4H8O)3 soln., flushed with CO (1-4.4 atm), maintained under CO during sonication at 10°C for 1000 min; not isolated, detected by IR;

DOI:10.1021/ja00334a073

Reference yield:

3Na(1+)*V(CO)5(3-)=Na3V(CO)5 → (hexacarbonyl)vanadinate(1-) (20644-87-5) + C5H3NO5V(1-) (45000-55-3) + 2Na(1+)*HV(CO)5(2-)=Na2HV(CO)5

Guidance literature:

With ethanol; In ammonia; a complex was treated with 1 equiv. of ethanol at -50°C;

DOI:10.1021/ja00329a070

upstream raw materials:

vanadium(III) chloride

(C₆H₅)3Sn*V(CO)6=(C₆H₅)3SnV(CO)6

methylacridinium hexacarbonylvanadate

trans-[V(phenyl acetylide)2(N,N,N',N'-tetramethylethylenediamine)2]

Downstream raw materials:

vanadium hexacarbonyl

iodo(triphenylphosphine)gold(I)

(CO)6V*AuP(C₆H₅)3=(CO)6VAuP(C₆H₅)3

(C₆H₅)3Sn*V(CO)6=(C₆H₅)3SnV(CO)6

Refernces

• 1、 Scott, Michael J.,Wilisch, Wolf Christian A.,Armstrong, William H.. "Unprecedented example of four coordination at a vanadium(II) center. Synthesis, structure, and properties of a reactive, nearly planar V(II) phenolate complex, [V(DIPP)4{Li(THF)}2] (DIPP = 2,6-diisopropylphenolate)". . p. 2429 - 2430. Retrieved 1990.
• 2、 Gailus, Hartmut,Woitha, Claus,Rehder, Dieter. "Dinitrogenvanadates(-1): Synthesis, Reactions and Conditions for their Stability". . p. 3471 - 3478. Retrieved 2007/10/02.